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Quaternary ammonium compounds in wastewater treatment effluents from 2020 to 2021

Metadata Updated: November 21, 2024

Quaternary ammonium compounds (QAC) are used in many commercial and household disinfection products. A method was developed to measure QAC occurrence in water discharged from three wastewater treatment plants during 2020 and 2021. Water samples (20 mL) were processed via solid phase extraction using weak cation exchange (WCX) cartridges (3 cc, 60 mg) and analyzed via liquid chromatography tandem mass spectrometry. Samples were analyzed for 12 QACs including benzethonium, six benzylalkyldimethyl ammonium compounds (BAC), three dialkyldimethyl ammonium compounds (DADMAC), and two ethylbenzylalkyldimethyl ammonium compounds (EBACs). QACs were detected in 100% of WWTP effluents with individual concentrations ranging 2.30-1,630 ng/L and total QAC concentrations (ΣQAC, the sum of 12 QAC) ranged 38.1-3,450 ng/L. The average concentrations of QACs detected in effluents was 49% BAC (average ΣBAC = 168 ng/L), 38% DADMAC (average ΣDADMAC = 119 ng/L), 9% EBACs (ΣEBAC = 25.0 ng/L), and 4% benzethonium (15.6 ng/L).

Access & Use Information

Public: This dataset is intended for public access and use. License: No license information was provided. If this work was prepared by an officer or employee of the United States government as part of that person's official duties it is considered a U.S. Government Work.

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Dates

Metadata Created Date November 19, 2024
Metadata Updated Date November 21, 2024

Metadata Source

Harvested from DOI EDI

Additional Metadata

Resource Type Dataset
Metadata Created Date November 19, 2024
Metadata Updated Date November 21, 2024
Publisher U.S. Geological Survey
Maintainer
@Id http://datainventory.doi.gov/id/dataset/9a9a69d8ac409fffc3fda5704b898db3
Identifier USGS:65af003fd34ef34c3506d8a8
Data Last Modified 20241119
Category geospatial
Public Access Level public
Bureau Code 010:12
Metadata Context https://project-open-data.cio.gov/v1.1/schema/catalog.jsonld
Metadata Catalog ID https://datainventory.doi.gov/data.json
Schema Version https://project-open-data.cio.gov/v1.1/schema
Catalog Describedby https://project-open-data.cio.gov/v1.1/schema/catalog.json
Harvest Object Id 430a27de-6f9b-496f-901f-b54a1abea140
Harvest Source Id 52bfcc16-6e15-478f-809a-b1bc76f1aeda
Harvest Source Title DOI EDI
Metadata Type geospatial
Old Spatial -80.2002,40.0444,-71.6748,45.89
Publisher Hierarchy White House > U.S. Department of the Interior > U.S. Geological Survey
Source Datajson Identifier True
Source Hash 66f1188a33e5fe4b57316a61106fe05ab9bdffdf27e3969db9d07e1364140cbb
Source Schema Version 1.1
Spatial {"type": "Polygon", "coordinates": -80.2002, 40.0444, -80.2002, 45.89, -71.6748, 45.89, -71.6748, 40.0444, -80.2002, 40.0444}

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