Local structure: Difference between revisions

Revision as of 07:42, 23 April 2021

Latest revision as of 22:47, 15 July 2022

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{{Short description|closeClose surroundings of an atom}}

[[File:Kristallstruktur Indiumoxid.png|thumb|upright=1.5|Crystal structure of indium(III) oxide]]

The '''local structure''' is a term in [[nuclear spectroscopy]] that refers to the structure of the nearest neighbours around an atom in [[crystal]]s and [[molecule]]s. E.g. in crystals the atoms order in a regular fashion on wide ranges to form even gigantic highly ordered crystals ([[Naica Mine]]). However, in reality, crystals are never perfect and have impurities or defects, which means that a foreign atom resides on a lattice site or in between lattice sites (interstitials). These small defects and impurities cannot be seen by methods such as [[X-ray diffraction]] or [[neutron diffraction]], because these methods average in their nature of measurement over a large number of atoms and thus are insensitive to effects in local structure. Methods in nuclear spectroscopy use specific [[Atomic nucleus|nuclei]] as probe. The nucleus of an [[atom]] is about 10,000 to 150,000 times smaller than the atom itself. It experiences the [[electric field gradient|electric fields]] created by the atom's electrons that surround the nucleus. In addition, the electric fields created by neighbouring atoms also influence the fields that the nucleus experiences. The interactions between the nucleus and these fields are called [[hyperfine structure|hyperfine interactions]] that influence the nucleus' properties. The nucleus therefore becomes very sensitive to small changes in its hyperfine structure, which can be measured by methods of nuclear spectroscopy, such as e.g. [[nuclear magnetic resonance]], [[Mössbauer spectroscopy]], and [[perturbed angular correlation]].

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[[Category:Quantum chemistry]]

[[Category:Electric and magnetic fields in matter]]

{{Quantum-chemistry-stub}}