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== quantum state versus wave function ==
First off, this article is pretty bad. For instance the lede is much too long and rambling. Hopefully, it can be improved. Before making any attempt to do so, I think it's worth figuring out a basic question regarding the subject of this article - what, precisely, is the distinction between a quantum state (for which we already have an article, namely [[quantum state]]), and a wave function?
The article (to the extent it's coherent at all) defines the wave function as a "complex-valued function", and refers to a representation of the state vector in some CSCO (complete set of commuting observables). But consider a particle in 1D QM, and express the state in the energy basis <i|\psi> (where H|i> = E_i | i>). That's a discrete set of complex numbers labeled by i - it's conceptually a lot more like a vector than a function. Furthermore it doesn't satisfy anything remotely resembling a wave equation. If one instead uses the position or momentum basis, <x|\psi> or <p|\psi>, that is a function and it does satisfy an equation that's a bit more like a wave equation.
So, if we define "wave function" to mean "state vector in any representation" as is done currently, it's (a) pretty much identical to "quantum state" and (b) in some representations it's neither a wave nor a function. Perhaps we should define it instead as the position representation <x|\psi>? One problem with that is that people use "wave function" more loosely than that - for example, "momentum space wavefunction". So instead, maybe we should define it as either <x|\psi> or <p|\psi>, but not other representations? Or just as any continuous representation? Comments? <small>'''<span style="color:Olive">Waleswatcher</span>''' [[User_talk:Waleswatcher#top|''(<span style="color:green">talk</span>)'']]</small> 12:55, 3 February 2016 (UTC)
:The present attitude of this article is that a state vector ([[pure state|pure quantum state]]) is characterized by a complete set of quantum numbers (superposition allowed!) and wave functions are projections of state vectors onto a ''complete set'' of state vectors, any which one. This is a very clean definition. It does include the energy expansion (whenever it applies). All representations satisfy the relevant Schrödinger equation, including the energy representation. (To see this, just expand the energy eigenstates in the position representation.) I don't want to change this ''attitude'', because it is "all inclusive" and, besides, it is correct except perhaps terminology-wise. We could change terminology in places. But thinking of functions as vectors in this context is something one has to get used to in the long run. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 13:54, 3 February 2016 (UTC)
:Weinberg uses the terminology "coefficient" or "coefficient function" in place of wave function in the context of QFT. We could do something with that (verifiably), and toss away such things as the energy representation under that label. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 13:59, 3 February 2016 (UTC)
:Hmm..., there are situations in which the interesting dynamics lies in the spin part of the wave function. I decidely do not want to exclude such cases by limiting the article to {{math|Ψ(''x'', ''t'')}}. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 14:15, 3 February 2016 (UTC)
:: Let me ask you this - would you ever write |\psi> = \sum c_i |i> , or <i|\psi> = c_i, and then refer to the c_i as a "wave function"? I wouldn't (because, as I said above, the c_i are neither a wave nor a function in any normal usage of those terms). However, I do agree that the term "wave function" can be used loosely to mean "quantum state", in whatever representation, and come to think of it I'm pretty sure while lecturing on QM I've uttered the phase "spin part of the wave function", for instance. What bugs me is that in that usage it's basically synonymous with quantum state, so doesn't really need its own article. <small>'''<span style="color:Olive">Waleswatcher</span>''' [[User_talk:Waleswatcher#top|''(<span style="color:green">talk</span>)'']]</small> 15:31, 3 February 2016 (UTC)
:::You are right about the terminology. I wouldn't call it a wave function. We could have an introductory section where proper (at least for all acceptable) terminology is established. Then the focus should be on position and momentum space, with sections devoted to energy representation, and exotic spin wave functions where we use terminology appropriate to ''them''. Just an idea. (Landau & Lifshitz use wave function for anything b t w - edit:meaning that they don't talk much about abstract ''states'' and Hilbert spaces. They work mostly with the image of Hilbert space in any coordinates (another Hilbert space)). I'm not fond of the idea of scrapping the article. It is too much to squeeze into quantum state (that has the additional burden of non-wave functions like mixed states). [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 15:50, 3 February 2016 (UTC)
::::I think there is a case for the article to distinguish between explicit and symbolic expressions of wave functions. In older texts, wave functions were expressed explicitly as functions of the relevant ___domain, as for example {{math|''ψ''('''r'''<sub>1</sub>, '''r'''<sub>2</sub>, ''t'') {{=}} ''α''<sub>1</sub> exp (−}}|{{math|'''r<sub>1</sub>'''}}|{{math|<sup>2</sup>) exp (−i''E''<sub>1</sub>''t''/''ħ'') + ''α''<sub>2</sub> exp (−}}|{{math|'''r<sub>2</sub>'''}}|{{math|<sup>2</sup>) exp (−i''E''<sub>2</sub>''t''/''ħ'')}}. A symbolic expression is, for example, in Dirac's notation, |{{math|''z''}}〉 = {{math|''ζ''<sub>1</sub>}}|{{math|''z''<sub>1</sub>}}〉 + {{math|''ζ''<sub>2</sub>}}|{{math|''z''<sub>2</sub>}}〉</noinclude> .[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 22:57, 3 February 2016 (UTC)
:::::The article does distinguish. It is wave functions versus states. Waleswatcher's point (and perhaps also mine), is that the distinction allows for too much to be dignified as wave functions. Perhaps we should redefine as (coefficients/coefficient functions/coordinate expressions/your name here) versus states, and that wave functions is a conventional subset of (coefficients/coefficient functions/coordinate expressions/your name here). Not everything as it is now. "Explicit and symbolic expressions" looks like your own invention of terminology. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 09:17, 4 February 2016 (UTC)
:::::Nipping the bud, in
::::::<math>|\Psi\rangle = I|\Psi\rangle = \int |x\rangle \langle x|\Psi\rangle dx = \int \Psi(x) |x\rangle dx = \int |p\rangle \langle p|\Psi\rangle dp = \int \Psi(p) |p\rangle dp,</math>
:::::it is the case that
::::::<math>|\Psi\rangle, |x\rangle, |p\rangle</math>
:::::are states, while
::::::<math>\Psi(x), \Psi(p)</math>
:::::are wave functions. There is never equality between states and wave functions. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 11:17, 4 February 2016 (UTC)
The use of bra-ket notation to give the position/momentum representations has been introduced more and more earlier in the article. Nothing wrong with it. I'm getting from this discussion that everything from [[Wave function#Discrete and continuous bases]] up to the ontology section is too general for this article and must be deleted? [[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 13:29, 4 February 2016 (UTC)
:<small>(The above is to demonstrate that Chjoaygame's invention of symbolic wave functions do not stand up to inspection.)</small> That conclusion has not been reached (yet). But at least change of terminology is probably preferred where appropriate.
:I have had a look at [[quantum state]]. In my mind, ''that'' article should deal exclusively with abstract states living in Hilbert space. ''This'' article should deal with states as viewed when projected onto a particular basis, and the machinery that comes with it. This is ''another'' Hilbert space, one for each choice of representation. Then the question is whether to limit coverage to position and momentum representations. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 13:46, 4 February 2016 (UTC)
::::::I didn't invent the term 'symbolic' in this context for this purpose. Dirac (4th edition 1958), an extract from the preface to the 1st (1930) edition:
:::::::::::With regard to the mathematical form in which the theory can be presented, an author must decide at the outset between two methods. There is the symbolic method, which deals directly in an abstract way with the quantities of fundamental importance (the invariants, etc., of the transformations) and there is the method of coordinates or representations, which deals with sets of numbers corresponding to these quantities. The second of these has usually been used for the presentation of quantum mechanics (in fact it has been used practically exclusively with the exception of Weyl's book ''Gruppentheorie und Quantenmechanik''). It is known under one or other of the two names 'Wave Mechanics' and 'Matrix Mechanics' according to which physical things receive emphasis in the treatment, the states of a system or its dynamical variables. It has the advantage that the kind of mathematics required is more familiar to the average student, and also it is the historical method.<ref>[[Paul Adrien Maurice Dirac|Dirac, P.A.M.]] (1958). ''The Principles of Quantum Mechanics'', 4th edition, Oxford University Press, Oxford UK, p. viii.</ref>
::::::Further on, Dirac writes
:::::::::::A further contraction may be made in the notation, namely to leave the symbol 〉 for the standard ket understood. A ket is then written simply as {{math|''ψ''(''ξ'')}}, a function of the observables {{math|''ξ''}}. A function of the {{math|''ξ''}}s used in this way to denote a ket is called a ''wave function''.† The system of notation provided by wave functions is the one usually used by most authors for calculations in quantum mechanics. In using it one should remember that each wave function is understood to have the standard ket multiplied into it on the right, which prevents one from multiplying the wave function by any operator on the right. ''Wave functions can be multiplied by operators only on the left.'' This distinguishes them from ordinary functions of the {{math|''ξ''}}s, which are operators and can be multiplied by operators on either the left or the right. A wave function is just the representative of a ket expressed as a function of the observables {{math|''ξ''}}, instead of eigenvalues {{math|''ξ′''}} for those observables.
::::::::::: † The reason for this name is that in the early days of quantum mechanics all the examples of these functions were of the form of waves. The name is not a descriptive one from the point of view of the modern general theory.<ref>[[Paul Adrien Maurice Dirac|Dirac, P.A.M.]] (1958). ''The Principles of Quantum Mechanics'', 4th edition, Oxford University Press, Oxford UK, p. 80.</ref>
::::::Messiah (1958):
:::::::::::Of the various ways of introducing the Quantum Theory, the one which uses the general formalism is undoubtedly the most elegant and the most satisfactory. However, it requires the handling of a mathematical symbolism whose abstract character runs the risk of masking the underlying physical reality. Wave Mechanics, which utilizes the more familiar language of waves and partial differential equations, lends itself better to a first encounter. Furthermore, it is in that form that the Quantum Theory is most frequently used in elementary applications. That is why we shall begin with a general outline of Wave Mechanics.<ref>[[Albert Messiah|Messiah, A.]] (1958/1961). ''Quantum Mechanics'', volume 1, translated by G.M. Temmer from the French ''Mécanique Quantique'', North-Holland, Amsterdam, p. 48.</ref>
::::::By 'wave function' Messiah (and many other texts) means something such as for example
:::::::::::... the matter wave
:::::::::::::::<math>\psi (\mathbf r_2, \tau_2) = \int K (\mathbf r_2 - \mathbf r_1; t_2 - t_1) \psi (\mathbf r_1, t_1) \, \mathrm d \mathbf r_1\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, (1)</math>
:::::::::::where
:::::::::::::::<math>K(\mathbf r, \tau) \,\,\,= (2\pi \hbar)^{{-3}} \int \exp \left [\frac {\mathrm i}{\hbar}(\mathbf p \cdot \mathbf r - E \tau)\right] \mathrm d \mathbf p.</math><ref>[[Albert Messiah|Messiah, A.]] (1958/1961). ''Quantum Mechanics'', volume 1, translated by G.M. Temmer from the French ''Mécanique Quantique'', North-Holland, Amsterdam, p. 75.</ref>
::::::Messiah does not feel a need for the ordinary-language word 'explicit' here because the situation seems obvious to him from what he has written, and he is not using the Dirac notation at that point, so as to need a contrast. I think for clarity for our purpose here an ordinary language word is needed to distinguish the two forms of expression. I did not invent the more technical term 'symbolic'; that is Dirac's. A symbolic expression is, for example, in Dirac's notation, |{{math|''z''}}〉 = {{math|''ζ''<sub>1</sub>}}|{{math|''z''<sub>1</sub>}}〉 + {{math|''ζ''<sub>2</sub>}}|{{math|''z''<sub>2</sub>}}〉 .
::::::Schrödinger invented wave functions and it may be fair to give an example from him. He writes
:::::::::::<math>(26^{\prime}) \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\psi_n (q) \,\,\,\,= e^{- \frac{2\pi^2\nu_0q^2}{h}} H_n \left (2\pi q \sqrt {\frac {\nu_0}{h}}\right)</math><ref>[[Erwin Schrödinger|Schrödinger, E.]] (1926). 'Quantisierung als Eigenwertproblem, Zweite Mitteilung', ''Annalen der Physik'', Series 4, '''79'''(6): 489–527.</ref>
::::::Weinberg in his ''Lectures'', on page 34, explicitly expresses a wave function as a function thus:
::::::::::::::::<math>\psi (\mathbf x) \,\,\,\,\,= R(r)Y(\theta,\phi) ,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, (2.1.21)</math><ref>[[Steven Weinberg|Weinberg, S.]] (2013). ''Lectures on Quantum Mechanics'', Cambridge University Press, Cambridge UK, {{ISBN|978-1-107-02872-2}}, p. 34.</ref>
'''References'''
{{Reflist}}
::::::What I am trying to draw attention to is not a distinction between two symbolic forms of expression. That distinction is, as you say, already drawn clearly by the article. The distinction I am pointing to is between a symbolic form, as labeled by Dirac, and a non-symbolic form (to use Dirac's words, "a function of the observables {{math|''ξ''}}, instead of eigenvalues {{math|''ξ′''}} for those observables") that I think ordinary language would call 'explicit'. I have now tried to indicate what I mean by two examples. If you think some ordinary-language word other than 'explicit' would be better, I have no prejudice. But I think some indicative word is needed for clarity.[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 16:25, 4 February 2016 (UTC)
:::::::And I think your references are too old to guide us at all in the choice of terminology. The "ordinary language" of yours have always had me confused. It could mean pretty much anything any given time. We should stick to present day terminology. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 09:32, 5 February 2016 (UTC)
Where ''should'' we draw the line on which representations or observables are relevant to the term "wavefunction"? There are canonical transformations on position and momentum. In solid state physics there are [[Bloch wave]]s which include wavevectors. We cannot rule out discrete representations, because in particle physics a wavefunction of a quark can be split into the product of spacetime, spin, and colour wavefunctions. There are others like isospin, in condensed matter physics there is something called [[pseudospin]] (no article?), in nuclear physics the nuclear angular momenta quantum number (the total angular momentum of all the nuclei), and in chemistry there are other angular momentum related quantum numbers (they are listed in Atkin's quanta book). Shouldn't "wavefunction" in general be defined as the component of a state vector (with discrete and/or continuous representations) ''which solves'' the SE or any other relativistic wave equation? [[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 11:54, 5 February 2016 (UTC)
:Perhaps we can handle this on a case by case basis. Waleswatcher's example of expansion coefficients in a countable energy representation is a good example of something rarely called a wave function. Your examples provide solid proof that there's more than the position and momentum representations called wave functions. Other than that, I am getting more and more convinced that the ''attitude'' of the present article (anything goes) is right. It is easier logically to present the full story. That said, the article really is badly organized, with a too bulky lead, and appropriate terminology can be introduced for things not usually called wave functions. By the way, is
::<math>\langle x|x'\rangle = x'(x) =\delta(x - x'),</math>
:the position eigenstate, a wave function? It does not satisfy the Schrödinger equation in the usual sense, but (OR{{smiley}}) it turns out that it does so in the sense of the left and the right side of the Scrödinger equation with {{math|''δ''(''x'' − ''x''′)}} plugged in being equal as distributions (or continuous linear functionals). When they act on [[wave packet]]s composed of free waves, they yield the same result. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 12:15, 5 February 2016 (UTC)
::I did not express myself clearly, indeed, I used faulty forms of expression. But still I have something to say, if I can put my ideas better.
::Above I gave an example of my idea of an explicit wave function: {{math|''ψ''('''r'''<sub>1</sub>, '''r'''<sub>2</sub>, ''t'') {{=}} ''α''<sub>1</sub> exp (−}}|{{math|'''r<sub>1</sub>'''}}|{{math|<sup>2</sup>) exp (−i''E''<sub>1</sub>''t''/''ħ'') + ''α''<sub>2</sub> exp (−}}|{{math|'''r<sub>2</sub>'''}}|{{math|<sup>2</sup>) exp (−i''E''<sub>2</sub>''t''/''ħ'')}}. I think many texts display objects more or less like that, and call them wave functions.
::And an example of a symbolic expression: |{{math|''z''}}〉 = {{math|''ζ''<sub>1</sub>}}|{{math|''z''<sub>1</sub>}}〉 + {{math|''ζ''<sub>2</sub>}}|{{math|''z''<sub>2</sub>}}〉.
::The symbolic expression is not a wave function, but it shows how a wave function is conceived in symbolic terms. The wave function, conceived there in symbolic terms is {{math|(''ζ''<sub>1</sub>, ''ζ''<sub>2</sub>)}}. The point is that, in this symbolic frame of thought, one doesn't think in terms of explicit wave functions, such as the one I just gave as an example. One thinks of the basis in terms of the kets, keeping consistently in the symbolic frame of thought, though the wave function itself doesn't actually write the kets. I think Dirac says that {{math|(''ζ''<sub>1</sub>, ''ζ''<sub>2</sub>)}} can be viewed as a function:
:::::::We may suppose the basic bras to be labelled by one or more parameters, {{math|''λ''<sub>1</sub>, ''λ''<sub>2</sub>, ... ''λ<sub>u</sub>''}}, each of which may take on certain numerical values. The basic bras will then be written 〈{{math|''λ''<sub>1</sub> ''λ''<sub>2</sub> ... ''λ<sub>u</sub>''}}| and the representative of |{{math|''a''}}〉 will be written 〈{{math|''λ''<sub>1</sub> ''λ''<sub>2</sub> ... ''λ<sub>u</sub>''}}|{{math|''a''}}〉. This representative will now consist of a set of numbers, one for each set of values that {{math|''λ''<sub>1</sub>, ''λ''<sub>2</sub>, ... ''λ<sub>u</sub>''}} may have in their respective domains. Such a set of numbers just forms a ''function'' of the variables {{math|''λ''<sub>1</sub>, ''λ''<sub>2</sub>, ... ''λ<sub>u</sub>''}}. Thus the representative of a ket may be looked upon either as a set of numbers or as a function of the variables used to label the basic bras.<4th edition, page 54.>
::I am sorry I didn't manage to express this clearly before now.[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 15:05, 5 February 2016 (UTC)
:::{{Reply to|YohanN7}} Sure, so long as the space of wave functions is extended to distributions. Incnis tried this a while ago. I was simply thinking of these quantities
::::<math>\Psi ( \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} ) </math>
:::from
::::<math>| \Psi \rangle = \sum_{s_{z\,1} , \ldots , s_{z\,N}}\int\limits\limits_{R_N} d^3\mathbf{r}_N \cdots \int\limits\limits_{R_1} d^3\mathbf{r}_1 \, \Psi ( \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} ) | \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} \rangle </math>
:::provided they solve the SE for the system, are called wavefunctions.
:::{{Reply to|Chjoaygame}} The expression you give is not dimensionally consistent in the exponential of position (you'd need to divide |'''r<sub>1</sub>'''|<sup>2</sup> and |'''r<sub>2</sub>'''|<sup>2</sup> each by a constant with units length<sup>2</sup> to get a number, then take the exponential). You seem to be making things quite complicated; yes a wavefunction is a complex-valued function, and the wavefunction is a function of these observables. The observables are also used to form a [[basis (linear algebra)|basis set]] of kets (one doesn't use a basis (basic?) bra like 〈{{math|''λ''<sub>1</sub> ''λ''<sub>2</sub> ... ''λ<sub>u</sub>''}}|). What you call "representative" is really a component of the state vector (see [[coordinate vector]]). What you call "symbolic expression" seem to just be kets. [[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 15:42, 5 February 2016 (UTC)
::::Sorry, I just wanted to give an example of the kind of thing, not complicate it with scaling factors. Yes, kets are symbols, that's how Dirac described them. I am not clear about what you write. It seems you are saying Dirac's statements about bras and kets are wrong?[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 16:48, 5 February 2016 (UTC)
:::::The modern terminology is this:
::::::<math>\underbrace{| \Psi \rangle}_{\text{state vector (ket)}} = \underbrace{\sum_{s_{z\,1} , \ldots , s_{z\,N}}\int\limits\limits_{R_N} d^3\mathbf{r}_N \cdots \int\limits\limits_{R_1} d^3\mathbf{r}_1}_{\text{adding up}} \, \underbrace{\Psi ( \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} )}_{\text{wavefunction (component of state vector)}} \underbrace{| \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} \rangle }_{\text{basis ket}}</math>
:::::We seem to just be using different terminology. Also you mentioned a bra as a particular basis element, but bras are not too important unless you calculate an inner product. All you need are kets; the corresponding bras can be obtained by taking the dual (Hermitian conjugate). I can't remember what Dirac wrote, will have to check in his Principles of quantum mechanics. [[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 17:15, 5 February 2016 (UTC)
:::::Forgot to mention bras are also important in forming operators in a given basis, and the completeness condition for manipulating bra-ket expressions, each are in this article and the [[bra-ket notation]] article. Otherwise kets come first, then taking duals of them. [[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 13:36, 6 February 2016 (UTC)
::::::[[User:Chjoaygame|Chjoaygame]], you know and I know that whatever we call things in the article, you'd chose to call it something else. That you can find the word "symbolic" in a foreword to a 193x book (even one by Dirac) is not even remotely notable. Yes, Dirac would be pretty damned loopy if he called state vectors (= kets) symbols. I don't think he did. If he did, then it is complicating simple matters beyond recognition and should forever be ignored. If you need to verbatim put things in an abstract setting (particular or any state vector in specified or unspecified Hilbert space with ''unspecified'' basis), then the word "abstract" is the way to go. Just like in the article. It is even ordinary language and ''should'' therefore be to your liking (had we not used it in the article of course).
::::::[[User:Maschen]]'s description above is the clearest and most spot on exposition of the proper concepts and terminology I have ever seen. This should go into the first section after the lead in the good article to be (whether verifiable or not). [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 10:18, 6 February 2016 (UTC)
::::::<math>\underbrace{| \Psi \rangle}_{\text{state vector (ket)}} = \underbrace{\overbrace{\sum_{s_{z\,1} , \ldots , s_{z\,N}}^{\text{discrete labels}}}\overbrace{\int\limits\limits_{R_N} d^3\mathbf{r}_N \cdots \int\limits\limits_{R_1} d^3\mathbf{r}_1}^{\text{continuous labels}}}_{\text{adding up}} \, \underbrace{\overbrace{\Psi}^{\text{wave function}} ( \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} )}_{\text{component of state vector along basis state}} \underbrace{| \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} \rangle }_{\text{basis state (basis ket)}}</math>
::::::[[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 12:44, 6 February 2016 (UTC)
:::::::{{reply to|YohanN7}} Thanks for feedback, and I like your elaborated version.
:::::::{{reply to|Chjoaygame}} Dirac's ''Principles of Quantum Mechanics'' 4th edition p.16, he uses both: "ket vectors or simply kets" to the name the vector, and "symbol {{ket|}}" for the symbols used in the notation (so it seems). In any case, this is a little pedantic and off-topic for this article. [[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 13:30, 6 February 2016 (UTC)
::::::::I wrote above "If you think some ordinary-language word other than 'explicit' would be better, I have no prejudice. But I think some indicative word is needed for clarity." That goes also for bras and kets; if Editor [[User:YohanN7|YohanN7]] thinks some other word than 'symbolic' would be better, I have no prejudice or attachment to it. Evidently he prefers 'abstract'. I have no problem with that. I used the word 'symbolic' just because I read it in Dirac and found it helpful. It has been used by others, some of whom have systematically presented both modes of expression. For example, Messiah on page 48: "However, it requires the handling of a mathematical symbolism whose abstract character runs the risk of masking the underlying physical reality."
::::::::Above I quoted from Dirac [https://archive.org/stream/DiracPrinciplesOfQuantumMechanics/Dirac%20-%20Principles%20of%20quantum%20mechanics#page/n63/mode/1up where he uses bras]. I didn't think that was a worry. I was surprised that Editor [[User:Maschen|Maschen]] objected to it. It is also to be found in the current version of the article:
:::::::::::::The wave function corresponding to an arbitrary state {{ket|Ψ}} is denoted
::::::::::::::<math>\langle a, b, \ldots, l, m, \ldots|\Psi\rangle,</math>
:::::::::::::for a concrete example,
::::::::::::::<math> \Psi(x) = \langle x|\Psi\rangle.</math>
::::::::I agree that Editor Maschen's formulation is admirable, and evidently Editor YohanN7 finds it fresh. I think it agrees with the [https://archive.org/stream/DiracPrinciplesOfQuantumMechanics/Dirac%20-%20Principles%20of%20quantum%20mechanics#page/n89/mode/1up page I quoted from Dirac], and have no worry about putting it in the article. I would suggest adjusting it slightly, to make it agree with Wikipedia definitions as follows:
::::::::<math>\underbrace{| \Psi \rangle}_{\text{state vector (ket)}} = \underbrace{\sum_{s_{z\,1} , \ldots , s_{z\,N}}\int\limits\limits_{R_N} d^3\mathbf{r}_N \cdots \int\limits\limits_{R_1} d^3\mathbf{r}_1}_{\text{adding up}} \, \underbrace{\Psi ( \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} )}_{\text{wavefunction (scalar projection of state vector)}} \underbrace{| \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} \rangle }_{\text{basis ket}}\,.</math>
::::::::I am suggesting to use the term [[scalar projection]].
::::::::Several comments have come in here while I have been writing this one. I agree with Editor YohanN7's adjustments to the admirable expression of Editor Maschen, and think that they could include my suggestion of using the term 'scalar projection' instead of 'component' without harm.[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 14:12, 6 February 2016 (UTC)
I too like Maschen's formula, but I think it is better with these labels - these are the same as YohanN7's improvement but without the separation of "wavefunction" from "component of state vector along basis state". Since those are the same thing and we are trying to define "wavefunction", I don't think we should separate them, and certainly not make it look as though \Psi and the arguments of \Psi are different objects.
<math>\underbrace{| \Psi \rangle}_{\text{state vector (ket)}} = \underbrace{\overbrace{\sum_{s_{z\,1} , \ldots , s_{z\,N}}^{\text{discrete labels}}}\overbrace{\int\limits\limits_{R_N} d^3\mathbf{r}_N \cdots \int\limits\limits_{R_1} d^3\mathbf{r}_1}^{\text{continuous labels}}}_{\text{adding up}} \, \underbrace{{\Psi}( \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} )}_{\text{wavefunction (component of state vector along basis state)}} \underbrace{| \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} \rangle }_{\text{basis state (basis ket)}}</math>
As for "scalar projection" - no. If anything, just "projection" - but "component" is probably better. <small>'''<span style="color:Olive">Waleswatcher</span>''' [[User_talk:Waleswatcher#top|''(<span style="color:green">talk</span>)'']]</small> 14:35, 6 February 2016 (UTC)
:No, a function, its arguments, and a function given an argument are three different objects. I know that it is standard in physics not to distinguish functions from functions given their arguments. But the mathematically inclined reader will get allergic reactions. Since the expression we are now cooking up is somewhat pretentious and strives for precision, we should not allow for any "terminologisms" particular to a field (math, phys, etc), except those almost forced upon us (Dirac notation is really superior here, but this is more of notation than terminology).
::<math>\underbrace{| \Psi \rangle}_{\text{state vector (ket)}} = \underbrace{\overbrace{\sum_{s_{z\,1} , \ldots , s_{z\,N}}^{\text{discrete labels}}}\overbrace{\int\limits\limits_{R_N} d^3\mathbf{r}_N \cdots \int\limits\limits_{R_1} d^3\mathbf{r}_1}^{\text{continuous labels}}}_{\text{adding up}} \, \underbrace{\overbrace{\Psi}^{\text{wave function}} \overbrace{(\mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} )}^{\text{eigenvalues of commuting observables}}}_{\text{component of state vector (complex number)}} \underbrace{| \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} \rangle }_{\text{basis state (basis ket)}}</math>
:[[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 09:23, 8 February 2016 (UTC)
{{reply to|Waleswatcher}} Sure, I'm not set on the exact labels and like your version better than mine.
{{reply to|Chjoaygame}} In
:<math>\langle a, b, \ldots, l, m, \ldots|\Psi\rangle </math>
what you are actually doing is start with {{ket|''a, b, ..., l, m,''}} then taking the dual to get the bra {{bra|''a, b, ..., l, m,''}} then taking the inner product of two kets {{ket|''a, b, ..., l, m,''}} and {{ket|Ψ}} (not a bra with a ket), in other words projecting {{ket|Ψ}} on {{ket|''a, b, ..., l, m,''}}, to obtain Ψ(''a, b, ..., l, m,''). This is what I wrote about above.
Now that hopefully clears up Chjoaygame's comments, it would be helpful to continue thinking about edits to improve the article. [[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 16:13, 6 February 2016 (UTC)
:Two ideas to get started de-cluttering and shortening the article:
:*A year ago the lead was a sensible length, and has since grown as others have noted. Maybe we could revert to an earlier version and tweak it (e.g. crisper clarification of spin, spinor, tensors, and degrees of freedom).
:*Either
:**All the cases for various numbers of particles, numbers of dimensions, no spin or spin (more generally other discrete variables) could be presented as complex valued functions and state vectors in braket notation. We need to decide other degrees of freedom are relevant for this article. Then all the general formalism of braket notation could be trimmed (most ideal, what is in [[bra-ket notation]] doesn't need to be in this article) or deleted entirely (not that I'm keen on that after writing much of it, but no matter).
:**Give the general formulation of continuous/discrete/mixed at the outset, then just give possible examples of what the continuous/discrete variables can be. (It may be compact, but unlikely to be favourable and less easy for typical readers to follow).
:[[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 16:44, 6 February 2016 (UTC)
::One can make plonking remarks about bras, relying on the mathematical point that Halmos calls the "brackets-to-parentheses revolution". The real targets of the plonking are, for example, Dirac, Weinberg, and Cohen-Tannoudji. They speak of the "scalar product". Gratifying though such plonking might be for mathematicians, it does not indicate physical understanding. The reason for distinguishing bras and kets is the physical distinction between preparation and observation of a quantum system, as indicated by Dirac.[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 10:19, 7 February 2016 (UTC)
::For example, in his paper 'Derivation of the Born rule from operational assumptions', [[Simon Saunders|Saunders]] writes:
::::::The kinds of experiments we shall consider are limited in the following respects: they are repeatable; there is a clear distinction between the state preparation device and the detection and registration device; and - this the most important limitation - we assume that for a given state-preparation device, preparing the system to be measured in a definite initial state, the state can be resolved into ''channels'', each of which can be independently blocked, in such a way that when only one channel is open the outcome of the experiment is ''deterministic'' - in the sense that if there is any registered outcome at all (on repetition of the experiment) it is always the ''same'' outcome.<ref>[[Simon Saunders|Saunders, S.]] (2004). 'Derivation of the Born rule from
operational assumptions', ''Proc. Roy. Soc. A'', '''460''': 1-18.</ref>
{{Reflist}}
::[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 10:49, 7 February 2016 (UTC)
::Ignoring yet more of Chjoaygame's experiments, channels, quotes, and now this time "plonking", all off-topic for this article, I'll amend my last post to be more specific.
::*Not to revert the entire article back to a 2015 or earlier stage, but just the lead. Maybe reinstate [https://en.wikipedia.org/w/index.php?title=Wave_function&oldid=640575092 this version of the lead] and tweak it from there.
::*Move the sections [[Wave function#More on wave functions and abstract state space]] (which includes the SE) and [[Wave function#Time dependence]] higher up to somewhere in [[Wave function#Wave functions and function spaces]] now that Dirac notation has been introduced earlier
::*merge the sections
::**[[Wave function#Definition (one spinless particle in 1d)]] + [[Wave function#State space for one spin-0 particle in 1d]]
::**[[Wave function#Definitions (other cases)]] + [[Wave function#State space (other cases)]] + [[Wave function#Tensor product]]
::*have a single section gathering all things on the probability interpretation, most specifically all requirements for the interpretation, and [[Wave function#Normalized components and probabilities]] in there
::*anything left over could be further rearranged, rewritten, moved to other articles, or deleted.
::In this article, giving the bra-ket notation for the specific examples should be enough for readers to get some idea how continuous/discrete representations are formulated. Generalities should be in the articles on [[bra-ket notation]], [[quantum state]], [[identical particles]], etc. [[user:Maschen|'''M''']][[User:Maschen/sandbox|'''∧''Ŝ''''']][[special:contributions/Maschen|''c''<sup>2</sup>''ħ''ε]][[user talk:maschen|''И<sub>τlk</sub>'']] 11:54, 7 February 2016 (UTC)
=== Proposal for dissection of definition of wave function ===
::<math>\underbrace{| \Psi \rangle}_{\text{state vector (ket)}} = \underbrace{\overbrace{\sum_{s_{z\,1} , \ldots , s_{z\,N}}^{\text{discrete labels}}}\overbrace{\int\limits\limits_{R_N} d^3\mathbf{r}_N \cdots \int\limits\limits_{R_1} d^3\mathbf{r}_1}^{\text{continuous labels}}}_{\text{adding up}} \, \underbrace{\overbrace{\Psi}^{\text{wave function}} \overbrace{(\mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} )}^{\text{eigenvalues of commuting observables}}}_{\text{component of state vector (complex number)}} \underbrace{| \mathbf{r}_1, \ldots, \mathbf{r}_N , s_{z\,1} , \ldots , s_{z\,N} \rangle }_{\text{basis state (basis ket)}}</math>
I am not religiously attached to the choice of any particular label, but I am a bit attached to the anatomy though, including the distinction between functions, their arguments, and their values. [[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 09:42, 8 February 2016 (UTC)
With these ingredients, the "local choice" in the article to always have the wave function scalar-valued as opposed to vector-valued (e.g. one entry for every spin z-component) makes a good measure of sense. It also helps making clear beyond any doubt what the ___domain and range of the wave function is (something that caused lengthy discussions here not long ago). Each of them corresponds to a brace.[[User:YohanN7|YohanN7]] ([[User talk:YohanN7|talk]]) 15:13, 8 February 2016 (UTC)
== Revision 2016-02-08 ==
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:Likely I am missing the main point here.
[[File:Quixo-panza.jpg
:::::<small class="autosigned">— Preceding [[Wikipedia:Signatures|unsigned]] comment added by [[Special:Contributions/194.68.82.241|194.68.82.241]] ([[User talk:194.68.82.241|talk]]) 13:55, 10 February 2016 (UTC)</small><!-- Template:Unsigned IP --> <!--Autosigned by SineBot--> Re-posted by [[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 14:19, 10 February 2016 (UTC)
:But anyway, here's a start. "How do you characterize a "maximal commuting set of observables"?" I think this is standard phrasing, at least in some places. One starts with some choice of observable. Then one chooses another. If they commute, it stays; if they don't, it's out. Repeat until one can't find any more that commute. I suppose that seems rather rough and ready, and hardly convincing. I will forthwith have a look to check this. Or is this utterly missing the point?[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 11:05, 10 February 2016 (UTC)
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:::::::German original (1932/1996), ''Mathematische Grundlagen der Quantenmechanik'', Springer, Berlin, ISBN-13: 978-3-642-64828-1, p. 79: "Einen Operator, der keine echten Fortsetzungen besitzt — der also an allen Stellen, wo er vernünftigerweise, d. h. ohne Durchbrechung des Hermiteschen Charakters, definiert werden könnte, auch schon definiert ist — nennen wir maximal. Wir haben also gesehen: nur zu maximalen Operatoren kann eine Zerlegung der Einheit gehören."[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 04:41, 11 February 2016 (UTC)
:::::::Newton, R.G. (2002), in ''Quantum Physics: a Text for Graduate Students'', Springer, New York, {{ISBN
:::::::Bransden, B.H., Joachain, C.J. (1989/2000), ''Quantum Mechanics'', second edition, Pearson–Prentice–Hall, Harlow UK, {{ISBN
:::::::[[Gennaro Auletta|Auletta, G.]], Fortunato, M., [[Giorgio Parisi|Parisi, G.]] (2009), ''Quantum Mechanics'', Cambridge University Press, Cambridge UK, {{ISBN
:::::::I Googled the phrase 'maximal set of commuting observables', and found [https://books.google.com.au/books?id=4ZwKCAAAQBAJ&pg=PA16&lpg=PA16&dq=maximal+set+of+commuting+observables+quantum+mechanics&source=bl&ots=ihL-ouMAoN&sig=iXg5Sm2CzApf0ZEKLZC0OsNO4Xk&hl=en&sa=X&ved=0ahUKEwiQg8GC6u7KAhVEkZQKHQ4qB_IQ6AEIMTAG#v=onepage&q=maximal%20set%20of%20commuting%20observables%20quantum%20mechanics&f=false this], and [https://books.google.com.au/books?id=lJaX2PsTxNoC&pg=PT94&lpg=PT94&dq=maximal+set+of+commuting+observables+quantum+mechanics&source=bl&ots=N7mHtcmXS9&sig=lIFMSkB-3JiMp3XG_yMjMaGqBAg&hl=en&sa=X&ved=0ahUKEwiQg8GC6u7KAhVEkZQKHQ4qB_IQ6AEILjAF#v=onepage&q=maximal%20set%20of%20commuting%20observables%20quantum%20mechanics&f=false also this], and [https://books.google.com.au/books?id=Xg2NZD73b4cC&pg=PA107&lpg=PA107&dq=maximal+set+of+commuting+observables+quantum+mechanics&source=bl&ots=XNpZbW3V-K&sig=hjtTtngz9OkXfbzrTtv2A4EeZA4&hl=en&sa=X&ved=0ahUKEwiQg8GC6u7KAhVEkZQKHQ4qB_IQ6AEIKjAE#v=onepage&q=maximal%20set%20of%20commuting%20observables%20quantum%20mechanics&f=false moreover this], and yet [https://books.google.com.au/books?id=eWdDAAAAQBAJ&pg=PA131&lpg=PA131&dq=maximal+set+of+commuting+observables+quantum+mechanics&source=bl&ots=5ICKajbc5X&sig=UHUeWc7xUNMAAFvJnAQlfR9MhMM&hl=en&sa=X&ved=0ahUKEwiQg8GC6u7KAhVEkZQKHQ4qB_IQ6AEIOTAI#v=onepage&q=maximal%20set%20of%20commuting%20observables%20quantum%20mechanics&f=false again this], and [https://books.google.com.au/books?id=v1owGsfiJcoC&pg=PA4&lpg=PA4&dq=maximal+set+of+commuting+observables+quantum+mechanics&source=bl&ots=k9hKAHG4-4&sig=wGW8ASjUSj6u_x9XrRjxzHZpvts&hl=en&sa=X&ved=0ahUKEwiQg8GC6u7KAhVEkZQKHQ4qB_IQ6AEIPDAJ#v=onepage&q=maximal%20set%20of%20commuting%20observables%20quantum%20mechanics&f=false now this].[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 04:18, 11 February 2016 (UTC)
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:"And how is "a state vector is an [[equivalence class]] of wave functions"?" I would have thought that was a standard way of expressing the situation. I learnt it when I studied algebra. It seems to be assumed as common mathematical parlance by the writer of this sentence: "Assuming that the unchanging reading of an ideal thermometer is a valid "tagging" system for the equivalence classes of a set of equilibrated thermodynamic systems, then if a thermometer gives the same reading for two systems, those two systems are in thermal equilibrium, and if we thermally connect the two systems, there will be no subsequent change in the state of either one." The sentence was posted in [https://en.wikipedia.org/w/index.php?title=Zeroth_law_of_thermodynamics&diff=next&oldid=667219209 this] edit by respected Editor [[User:PAR|PAR]]. My usage intends that all the wave functions that belong to a particular state are interconvertible by a group of one-to-one mathematical transformations. That makes them members of an equivalence class. (The equivalence class has the structure of a Hilbert space, more or less.) I find this form of expression helpful to show the relation between wave functions and state vectors. It may or may not be so for others.[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 09:39, 14 February 2016 (UTC)
:Well, it seems that I have led myself astray by looking in Wikipedia and Google. Looking at a textbook on my shelves that I forgot I had, I find that indeed, as you say, a component is there defined as a scalar. Bloom, D.M. (1979), ''Linear Algebra and Geometry'', Cambridge University Press, Cambridge UK, {{ISBN
:See [[Talk:Scalar projection#This article has gravely misled me, and helped to make me look foolish, because I thought that on such a simple matter, an article like this could be trusted.]][[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 12:59, 14 February 2016 (UTC)
:Also [[Talk:Basis (linear algebra)/Archive 1#customary terminology not clear in Wikipedia; local editors, heads up]].[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 18:17, 14 February 2016 (UTC)
:Perhaps I went overboard with the ''mea culpa''. Looking a bit further, I get the impression that customs vary.[[User:Chjoaygame|Chjoaygame]] ([[User talk:Chjoaygame|talk]]) 19:26, 14 February 2016 (UTC)
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:::Though, a reader interested only in [[Linear combination of atomic orbitals]] needs less... [[User:Tsirel|Boris Tsirelson]] ([[User talk:Tsirel|talk]]) 12:53, 16 February 2016 (UTC)
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