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{{Short description|Problem in astronomy}}
In [[astronomy]], the '''lithium problem''' or '''lithium discrepancy''' refers to the discrepancy between the primordial [[Abundance of the chemical elements|abundance]] of [[lithium]] as inferred from observations of metal-poor ([[Stellar population|Population II]]) [[Stellar halo|halo stars]] in our galaxy and the amount that should theoretically exist due to [[Big Bang nucleosynthesis]]+[[Wilkinson Microwave Anisotropy Probe|WMAP]] cosmic baryon density predictions of the [[
[[File:Schramm plot BBN review 2019.png|thumb|400px|This "Schramm plot"<ref>{{cite journal | last1=Tanabashi | first1=M. | last2=Hagiwara | first2=K. | last3=Hikasa | first3=K. | last4=Nakamura | first4=K. | last5=Sumino | first5=Y. | last6=Takahashi | first6=F. | last7=Tanaka | first7=J. | last8=Agashe | first8=K. | last9=Aielli | first9=G. | last10=Amsler | first10=C. | display-authors=5|collaboration=Particle Data Group| title=Review of Particle Physics | journal=Physical Review D | publisher=American Physical Society (APS) | volume=98 | issue=3 | date=2018-08-17 | issn=2470-0010 | doi=10.1103/physrevd.98.030001 | page=030001| bibcode=2018PhRvD..98c0001T |doi-access=free| hdl=10044/1/68623 | hdl-access=free }} and 2019 update.</ref> depicts primordial abundances of <sup>4</sup>He, D, <sup>3</sup>He, and <sup>7</sup>Li as a function of cosmic baryon content from standard BBN predictions. CMB predictions of <sup>7</sup>Li (narrow vertical bands, at 95% [[confidence level|CL]]) and the BBN D + <sup>4</sup>He concordance range (wider vertical bands, at 95% CL) should overlap with the observed light element abundances (yellow boxes) to be in agreement. This occurs in <sup>4</sup>He and is well constrained in D, but is not the case for <sup>7</sup>Li, where the observed Li observations lie a factor of 3−4 below the BBN+WMAP prediction.]]
==Origin of lithium==
Minutes after the Big Bang, the universe was made almost entirely of hydrogen and helium, with trace amounts of lithium and beryllium, and negligibly small abundances of all heavier elements.<ref name="habitable"/><ref>{{cite web|url=https://physics.unc.edu/the-cosmological-lithium-problem/|title=Cosmological lithium problem|website=University of North Carolina|date=14 September 2020 }}</ref>
===Lithium synthesis in the Big Bang===
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The amount of lithium generated in the Big Bang can be calculated.<ref>{{cite journal | bibcode= 1985ARA&A..23..319B | title= Big bang nucleosynthesis – Theories and observations | last1= Boesgaard | first1=A. M. | last2= Steigman | first2= G. | volume= 23 |date= 1985 | pages= 319–378 | journal= [[Annual Review of Astronomy and Astrophysics]] |id=A86-14507 04–90 |___location=Palo Alto, CA | doi= 10.1146/annurev.aa.23.090185.001535}}</ref> [[Hydrogen-1]] is the most abundant [[nuclide]], comprising roughly 92% of the atoms in the Universe, with [[helium-4]] second at 8%. Other isotopes including <sup>2</sup>H, <sup>3</sup>H, <sup>3</sup>He, <sup>6</sup>Li, <sup>7</sup>Li, and <sup>7</sup>Be are much rarer; the estimated abundance of primordial lithium is 10<sup>−10</sup> relative to hydrogen.<ref name=23bbn>{{cite book |last1=Tanabashi |first1=M. |display-authors=et al. |editor-last1=Fields |editor-first1=B. D. |editor-last2=Molaro |editor-first2=P. |editor-last3=Sarkar |editor-first3=S. |title=The Review |date=2018 |chapter=Big-bang nucleosynthesis |journal=Physical Review D |volume=98 |issue=3 |pages=377–382 |doi=10.1103/PhysRevD.98.030001 |bibcode=2018PhRvD..98c0001T |url=https://pdg.lbl.gov/2019/reviews/rpp2018-rev-bbang-nucleosynthesis.pdf
}}</ref> The calculated abundance and ratio of <sup>1</sup>H and <sup>4</sup>He is in agreement with data from observations of young stars.<ref name="habitable">{{cite book |isbn=978-0691140063|title=How to Build a Habitable Planet: The Story of Earth from the Big Bang to Humankind|last1=Langmuir|first1=C. H.|last2=Broecker|first2=W. S.|year=2012|publisher=Princeton University Press }}</ref>
===The P-P II branch===
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[[File:Nova Centauri 2013 ESO.jpg|thumb|[[Nova Centauri 2013]] is the first in which evidence of lithium has been found.<ref>{{cite web|title=First Detection of Lithium from an Exploding Star|url=http://www.eso.org/public/news/eso1531/|accessdate=29 July 2015|url-status=dead|archiveurl=https://web.archive.org/web/20150801001700/http://www.eso.org/public/news/eso1531/|archivedate=1 August 2015|df=dmy-all}}</ref>]]
Lithium is also found in [[brown dwarf]] substellar objects and certain anomalous
===Less lithium in Sun-like stars with planets===
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|arxiv = 0911.4198
|s2cid=388656
|quote=<span style="font-family:LatinModern;"><small>... confirm the peculiar behaviour of Li in the effective temperature range 5600–5900 K ... We found that the immense majority of planet host stars have severely depleted lithium ... At higher and lower temperatures planet-host stars do not appear to show any peculiar behaviour in their Li abundance.</small></span>}}</ref> The Sun's surface layers have less than 1% the lithium of the original formation [[Formation and evolution of the Solar System#Formation|protosolar gas clouds]] despite the surface convective zone not being quite hot enough to burn lithium.<ref name = "Israelian"/> It is suspected that the gravitational pull of planets might enhance the churning up of the star's surface, driving the lithium to hotter cores where [[lithium burning]] occurs.<ref name="Discover"/><ref name = "Israelian"/> The absence of lithium could also be a way to find new planetary systems.<ref name="Discover"/> However, this claimed relationship has become a point of contention in the planetary astrophysics community, being frequently denied<ref name="BaumannRamírez2010">{{cite journal|last1=Baumann|first1=P.|last2=Ramírez|first2=I.|last3=Meléndez|first3=J.|last4=Asplund|first4=M.|last5=Lind|first5=K.|display-authors=2|title=Lithium depletion in solar-like stars: no planet connection|journal=Astronomy and Astrophysics|volume=519|year=2010|pages=A87|issn=0004-6361|doi=10.1051/0004-6361/201015137|arxiv=1008.0575 |bibcode=2010A&A...519A..87B |doi-access=free}}</ref><ref name="RamírezFish2012">{{cite journal|last1=Ramírez|first1=I.|last2=Fish|first2=J. R.|last3=Lambert|first3=D. L.|last4=Allende Prieto|first4=C.|display-authors=2|title=Lithium abundances in nearby FGK dwarf and subgiant stars: internal destruction, galactic chemical evolution, and exoplanets|journal=The Astrophysical Journal|volume=756|issue=1|year=2012|pages=46|issn=0004-637X|doi=10.1088/0004-637X/756/1/46|arxiv=1207.0499 |bibcode=2012ApJ...756...46R |hdl=2152/34872|s2cid=119199829 |hdl-access=free}}</ref> but also supported.<ref name="FigueiraFaria2014">{{cite journal|last1=Figueira|first1=P.|last2=Faria|first2=J. P.|last3=Delgado-Mena|first3=E.|last4=Adibekyan|first4=V. Zh.|last5=Sousa|first5=S. G.|last6=Santos|first6=N. C.|last7=Israelian|first7=G.|display-authors=2|title=Exoplanet hosts reveal lithium depletion|journal=Astronomy & Astrophysics|volume=570|year=2014|pages=A21|issn=0004-6361|doi=10.1051/0004-6361/201424218|doi-access=free|arxiv=1409.0890}}</ref><ref name="Delgado MenaIsraelian2014">{{cite journal|last1=Delgado Mena|first1=E.|last2=Israelian|first2=G.|last3=González Hernández|first3=J. I.|last4=Sousa|first4=S. G.|last5=Mortier|first5=A.|last6=Santos|first6=N. C.|last7=Adibekyan|first7=V. Zh.|last8=Fernandes|first8=J.|last9=Rebolo|first9=R.|last10=Udry|first10=S.|last11=Mayor|first11=M.|display-authors=2|title=Li depletion in solar analogues with exoplanets|journal=Astronomy & Astrophysics|volume=562|year=2014|pages=A92|issn=0004-6361|doi=10.1051/0004-6361/201321493|doi-access=free|arxiv=1311.6414}}</ref>
===Higher than expected lithium in metal-poor stars===
Certain
==Proposed solutions==
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Considering the possibility that BBN predictions are sound, the measured value of the primordial lithium abundance should be in error and astrophysical solutions offer revision to it. For example, systematic errors, including ionization correction and inaccurate stellar temperatures determination could affect Li/H ratios in stars. Furthermore, more observations on lithium depletion remain important since present lithium levels might not reflect the initial abundance in the star. In summary, accurate measurements of the primordial lithium abundance is the current focus of progress, and it could be possible that the final answer does not lie in astrophysical solutions.<ref name="fields11" />
Some astronomers suggest that the velocities of nucleons do not follow a [[Maxwell-Boltzmann distribution]]. They test the framework of Tsallis non-extensive statistics. Their result suggest that {{nowrap|1.069 < q < 1.082}} is a possible new solution to the cosmological lithium problem.<ref>{{Cite journal |
=== Nuclear physics solutions ===
When one considers the possibility that the measured primordial
Firstly, incorrect or missing reactions could give rise to the lithium problem. For incorrect reactions, major thoughts lie within revision to [[cross section (physics)|cross section]] errors and standard thermonuclear rates according to recent studies.<ref>{{Cite journal|last1=Angulo|first1=C.|last2=Casarejos|first2=E.|last3=Couder|first3=M.|last4=Demaret|first4=P.|last5=Leleux|first5=P.|last6=Vanderbist|first6=F.|last7=Coc|first7=A.|last8=Kiener|first8=J.|last9=Tatischeff|first9=V.|last10=Davinson|first10=T.|last11=Murphy|first11=A. S.|date=September 2005|title=The 7Be(d,p)2α Cross Section at Big Bang Energies and the Primordial 7Li Abundance|journal=Astrophysical Journal Letters|language=en|volume=630|issue=2|pages=L105–L108|doi=10.1086/491732|arxiv=astro-ph/0508454 |bibcode=2005ApJ...630L.105A |issn=0004-637X|doi-access=free}}</ref><ref>{{Cite journal|last1=Boyd|first1=Richard N.|last2=Brune|first2=Carl R.|last3=Fuller|first3=George M.|last4=Smith|first4=Christel J.|date=November 2010|title=New nuclear physics for big bang nucleosynthesis|url=https://ui.adsabs.harvard.edu/abs/2010PhRvD..82j5005B/abstract|journal=Physical Review D |language=en|volume=82|issue=10|pages=105005|doi=10.1103/PhysRevD.82.105005|issn=1550-7998|arxiv=1008.0848|bibcode=2010PhRvD..82j5005B |s2cid=119265813 }}</ref>
Second, starting from [[Fred Hoyle]]'s discovery of a [[Resonance (particle physics)|resonance]] in [[carbon-12]], an important factor in the [[triple-alpha process]], resonance reactions, some of which might have evaded experimental detection or whose effects have been underestimated, become possible solutions to the lithium problem.<ref>{{Cite journal|last1=Hammache|first1=F.|last2=Coc|first2=A.|last3=de Séréville|first3=N.|last4=Stefan|first4=I.|last5=Roussel|first5=P.|last6=Ancelin|first6=S.|last7=Assié|first7=M.|last8=Audouin|first8=L.|last9=Beaumel|first9=D.|last10=Franchoo|first10=S.|last11=Fernandez-Dominguez|first11=B.|date=December 2013|title=Search for new resonant states in 10C and 11C and their impact on the cosmological lithium problem|url=https://ui.adsabs.harvard.edu/abs/2013PhRvC..88f2802H/abstract|journal=Physical Review C|language=en|volume=88|issue=6|pages=062802|doi=10.1103/PhysRevC.88.062802|issn=0556-2813|arxiv=1312.0894|bibcode=2013PhRvC..88f2802H |s2cid=119110688 }}</ref><ref>{{Cite journal|last1=O'Malley|first1=P. D.|last2=Bardayan|first2=D. W.|last3=Adekola|first3=A. S.|last4=Ahn|first4=S.|last5=Chae|first5=K. Y.|last6=Cizewski|first6=J. A.|author6-link= Jolie Cizewski |last7=Graves|first7=S.|last8=Howard|first8=M. E.|last9=Jones|first9=K. L.|last10=Kozub|first10=R. L.|last11=Lindhardt|first11=L.|date=October 2011|title=Search for a resonant enhancement of the 7Be + d reaction and primordial 7Li abundances|url=https://ui.adsabs.harvard.edu/abs/2011PhRvC..84d2801O/abstract|journal=Physical Review C|language=en|volume=84|issue=4|pages=042801|doi=10.1103/PhysRevC.84.042801|bibcode=2011PhRvC..84d2801O |issn=0556-2813}}</ref> These include:
{| border="0"
|- style="height:2em;"
|{{nuclide|link=yes|beryllium|7}} ||+ ||{{nuclide|link=yes|hydrogen|2}} ||→ ||{{nuclide|link=yes|boron|9}} *
|- style="height:2em;"
|{{nuclide|link=yes|beryllium|7}} ||+ ||{{nuclide|link=yes|hydrogen|3}} ||→ ||{{nuclide|link=yes|boron|10}} *
|-
|{{nuclide|link=yes|beryllium|7}}
| +
|{{nuclide|link=yes|helium|3}}
|→
|{{nuclide|link=yes|carbon|10}} *
|}Experimental and theoretical analyses rule out the first and third reactions.<ref name="o946">{{cite journal |last=Cyburt |first=Richard H. |last2=Fields |first2=Brian D. |last3=Olive |first3=Keith A. |last4=Yeh |first4=Tsung-Han |date=2016-02-23 |title=Big bang nucleosynthesis: Present status |url=https://link.aps.org/accepted/10.1103/RevModPhys.88.015004 |journal=Reviews of Modern Physics |volume=88 |issue=1 |page= |doi=10.1103/RevModPhys.88.015004 |issn=0034-6861 |access-date=2025-03-30 |doi-access=free|arxiv=1505.01076 }}</ref>
''[[BBC Science Focus]]'' wrote in 2023 that "recent research seems to completely discount" such theories; the magazine held that mainstream lithium nucleosynthesis calculations are probably correct.<ref name=BBC2023>{{cite news |url=https://www.sciencefocus.com/science/lithium-shortage-universe/ |title=The lithium problem: Why the element keeps disappearing |work=BBC Science Focus Magazine |date=16 June 2023 |author=Alastair Gunn |access-date=17 June 2023}}</ref>
=== Solutions beyond the Standard Model ===
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Dark matter decay and [[supersymmetry]] provide one possibility, in which decaying dark matter scenarios introduce a rich array of novel processes that can alter light elements during and after BBN, and find the well-motivated origin in supersymmetric cosmologies. With the fully operational [[Large Hadron Collider]] (LHC), much of minimal supersymmetry lies within reach, which would revolutionize particle physics and cosmology if discovered;<ref name="fields11" /> however, results from the ATLAS experiment in 2020 have excluded many supersymmetric models.<ref>{{Cite journal|last=Collaboration|first=Atlas|year=2021|title=Search for squarks and gluinos in final states with jets and missing transverse momentum using 139 fb$^{-1}$ of $\sqrt{s}$ =13 TeV $pp$ collision data with the ATLAS detector|journal=Jhep |volume=02 |page=143 |language=en|doi=10.1007/JHEP02(2021)143|arxiv=2010.14293 |s2cid=256039464 }}</ref><ref>{{Cite web|last=Sutter|first=Paul|date=2021-01-07|title=From squarks to gluinos: It's not looking good for supersymmetry|url=https://www.space.com/no-signs-supersymmetry-large-hadron-collider|access-date=2021-10-29|website=Space.com|language=en}}</ref>
Changing [[fundamental constants]] can be one possible solution, and it implies that first, atomic transitions in metals residing in high-[[redshift]] regions might behave differently from our own. Additionally, Standard Model couplings and particle masses might vary
Nonstandard cosmologies indicate variation of the baryon to photon ratio in different regions. One proposal is a result of large-scale inhomogeneities in cosmic density, different from homogeneity defined in the [[cosmological principle]]. However, this possibility requires a large amount of observations to test it.<ref>{{Cite journal|last1=Holder|first1=Gilbert P.|last2=Nollett|first2=Kenneth M.|last3=van Engelen|first3=Alexander|date=June 2010|title=On Possible Variation in the Cosmological Baryon Fraction|journal=Astrophysical Journal|language=en|volume=716|issue=2|pages=907–913|doi=10.1088/0004-637X/716/2/907|arxiv=0907.3919 |bibcode=2010ApJ...716..907H |issn=0004-637X|doi-access=free}}</ref>
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* [[List of unsolved problems in physics]]
* [[Lithium burning]]
==Further reading==
* {{cite journal |last1=Fields |first1=Brian D. |title=The Primordial Lithium Problem |journal=Annual Review of Nuclear and Particle Science |volume=61 |year=2011 |pages=47–68 |doi=10.1146/annurev-nucl-102010-130445 |arxiv=1203.3551|bibcode=2011ARNPS..61...47F }}
* {{cite journal |doi=10.1103/PhysRevD.83.063006 |title=Resonant destruction as a possible solution to the cosmological lithium problem |date=2011 |last1=Chakraborty |first1=Nachiketa |last2=Fields |first2=Brian D. |last3=Olive |first3=Keith A. |journal=Physical Review D |volume=83 |issue=6 |page=063006 |arxiv=1011.0722 |bibcode=2011PhRvD..83f3006C }}
* {{cite journal |doi=10.1142/S0218301312500048 |title=Resonant Enhancement of Nuclear Reactions as a Possible Solution to the Cosmological Lithium Problem |date=2012 |last1=Cyburt |first1=Richard H. |last2=Pospelov |first2=Maxim |journal=International Journal of Modern Physics E |volume=21 |issue=1 |pages=1250004-1-1250004-13 |arxiv=0906.4373 |bibcode=2012IJMPE..2150004C }}
* {{cite journal |last1=Hou |first1=S. Q. |last2=Yan |first2=H. L. |last3=Li |first3=X. Y. |last4=Zhou |first4=X. H. |last5=Sun |first5=B. |title=Non-Extensive Statistics to the Cosmological Lithium Problem |journal=The Astrophysical Journal |volume=834 |issue=2 |year=2017 |pages=165 |doi=10.3847/1538-4357/834/2/165 |doi-access=free |arxiv=1701.03700|bibcode=2017ApJ...834..165H }}
==References==
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