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{{Short description|Property of an object or substance to transmit light with minimal scattering}}
{{
[[File:Dichroic filters.jpg|thumb|right|[[Dichroic filter]]s are created using optically transparent materials.]]
In the field of [[optics]], '''transparency''' (also called '''pellucidity''' or '''diaphaneity''') is the [[physical property]] of allowing [[light]] to pass through the material without appreciable [[light scattering by particles|scattering of light]]. On a [[macroscopic scale]] (one in which the dimensions are much larger than the wavelengths of the [[photon]]s in question), the photons can be said to follow [[Snell's law]]. '''Translucency''' (also called '''translucence''' or '''translucidity''')
When light encounters a material, it can interact with it in several different ways. These interactions depend on the [[wavelength]] of the light and the nature of the material. Photons interact with an object by some combination of reflection, absorption and transmission.
Some materials, such as [[plate glass]] and clean [[water]], transmit much of the light that falls on them and reflect little of it; such materials are called optically transparent. Many liquids and aqueous solutions are highly transparent. Absence of structural defects (voids, cracks, etc.) and molecular structure of most liquids are mostly responsible for excellent optical transmission.
Materials
Transparency can provide almost perfect [[camouflage]] for animals <!--or possibly military equipment?--> able to achieve it. This is easier in dimly-lit or turbid [[sea]]water than in good illumination. Many [[marine biology|marine animals]] such as [[jellyfish]] are highly transparent.
[[File:Opacity Translucency Transparency.svg|thumb|250px|right|Comparisons of 1. opacity, 2. translucency with scattering, and 3. transparency; behind each panel (from top to bottom: grey, red, white) is a star.]]
== Etymology ==
* late Middle English: from Old French, from medieval Latin {{lang|la|transparent}}-
* late 16th century (in the Latin sense): from Latin {{lang|la|translucent}}-
* late Middle English {{lang|enm|opake}}, from Latin {{lang|la|opacus}}
== Introduction ==
{{More citations needed section|date=April 2021}}
With regard to the absorption of light, primary material considerations include:
* At the electronic level, absorption in the [[ultraviolet]] and visible (UV-Vis) portions of the spectrum depends on whether the [[Atomic orbital|electron orbitals]] are spaced (or "quantized") such that
* At the atomic or molecular level, physical absorption in the infrared portion of the spectrum depends on the [[frequencies]] of atomic or [[molecular vibrations]] or [[chemical bonds]], and on [[selection rule]]s. Nitrogen and oxygen are not greenhouse gases because there is no [[molecular dipole moment]].
{{np}}{{pb}}
With regard to the [[light scattering in liquids and solids|scattering of light]], the most critical factor is the length scale of any or all of these structural features relative to the wavelength of the light being scattered. Primary material considerations include:
* Crystalline structure: whether the atoms or molecules exhibit the 'long-range order' evidenced in crystalline solids.▼
▲*Crystalline structure: whether the atoms or molecules exhibit the 'long-range order' evidenced in crystalline solids.
* [[Microstructure]]: Scattering centers include internal surfaces such as grain boundaries, [[crystallographic defect]]s, and microscopic pores.
▲*Glassy structure: scattering centers include fluctuations in density or composition.
*
{{Main|Light scattering}}
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[[File:Diffuse refl.gif|thumb|right|250px|General mechanism of '''diffuse reflection''']]
[[Diffuse reflection]] - Generally, when light strikes the surface of a (non-metallic and non-glassy) solid material, it bounces off in all directions due to multiple reflections by the microscopic irregularities ''inside'' the material (e.g., the [[grain boundaries]] of a [[polycrystalline]] material
|author=Mandelstam, L.I.|title=Light Scattering by Inhomogeneous Media
|journal=Zh. Russ. Fiz-Khim. Ova.
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|year=1926}}</ref>
Light scattering in liquids and solids depends on the wavelength of the light being scattered. Limits to spatial scales of visibility (using white light) therefore arise, depending on the frequency of the light wave and the physical [[dimension]] (or spatial scale) of the scattering center. Visible light has a wavelength scale on the order of
=== Transparent ceramics ===
Optical transparency in polycrystalline materials is limited by the amount of light
In the formation of polycrystalline materials (metals and ceramics) the size of the crystalline grains is determined largely by the size of the crystalline particles present in the raw material during formation (or pressing) of the object. Moreover, the size of the grain boundaries scales directly with particle size. Thus, a reduction of the original particle size well below the wavelength of visible light (about 1/15 of the light wavelength, or roughly 600 nm / 15 = 40 [[
Computer modeling of light transmission through translucent ceramic alumina has shown that microscopic pores trapped near grain boundaries act as primary scattering centers. The volume fraction of porosity had to be reduced below 1% for high-quality optical transmission (99.99 percent of theoretical density). This goal has been readily accomplished and amply demonstrated in laboratories and research facilities worldwide using the emerging chemical processing methods encompassed by the methods of [[sol-gel]] chemistry and [[nanotechnology]].<ref>{{cite journal|author=Yamashita, I.|title=Transparent Ceramics|journal=J. Am. Ceram. Soc.|volume=91|issue=3|page=813|year=2008|doi=10.1111/j.1551-2916.2007.02202.x|display-authors=etal}}</ref>
[[Image:Backlit mushroom.jpg|thumb|Translucency of a material being used to highlight the structure of a
[[Transparent ceramic]]s have created interest in their applications for high energy lasers, transparent armor windows, nose cones for heat seeking missiles, radiation detectors for non-destructive testing, high energy physics, space exploration, security and medical imaging applications. Large [[laser]] elements made from transparent ceramics can be produced at a relatively low cost. These components are free of internal [[Stress (mechanics)|stress]] or intrinsic [[birefringence]], and allow relatively large doping levels or optimized custom-designed doping profiles. This makes ceramic laser elements particularly important for high-energy lasers.
The development of transparent panel products will have other potential advanced applications including high strength, impact-resistant materials that can be used for domestic windows and skylights. Perhaps more important is that walls and other applications will have improved overall strength, especially for high-shear conditions found in high seismic and wind exposures. If the expected improvements in mechanical properties bear out, the traditional limits seen on glazing areas in today's building codes could quickly become outdated if the window area actually contributes to the shear resistance of the wall.
Currently available infrared transparent materials typically exhibit a trade-off between optical performance, mechanical strength and price. For example, [[sapphire]] (crystalline [[alumina]]) is very strong, but it is expensive and lacks full transparency throughout the 3–5
== Absorption of light in solids ==
{{More citations needed section|date=April 2021}}
When light strikes an object, it usually has not just a single frequency (or wavelength) but many. Objects have a tendency to selectively absorb, reflect, or transmit light of certain frequencies. That is, one object might reflect green light while absorbing all other frequencies of visible light. Another object might selectively transmit blue light while absorbing all other frequencies of visible light. The manner in which visible light interacts with an object is dependent upon the frequency of the light, the nature of the atoms in the object, and often, the nature of the [[electron]]s in the [[atom]]s of the object.
Some materials allow much of the light that falls on them to be transmitted through the material without being reflected. Materials that allow the transmission of light waves through them are called optically transparent. Chemically pure (undoped) window glass and clean river or spring water are prime examples of this.
Materials
Absorption centers are largely responsible for the appearance of specific wavelengths of visible light all around us. Moving from longer (0.7
*Electronic: Transitions in electron [[energy levels]] within the atom (e.g., [[pigments]]). These transitions are typically in the ultraviolet (UV) and/or visible portions of the spectrum.
*Vibrational: [[Resonance]] in atomic/molecular [[vibrational modes]]. These transitions are typically in the infrared portion of the spectrum.
=== UV-Vis:
In electronic absorption, the frequency of the incoming light wave is at or near the energy levels of the electrons within the atoms
The atoms that bind together to make the molecules of any particular substance contain a number of electrons (given by the [[atomic number]] Z in the [[periodic
* A molecule absorbs the photon, some of the energy may be lost via [[luminescence]], [[fluorescence]] and [[phosphorescence]].▼
* A molecule absorbs the photon, which results in reflection or scattering.▼
* A molecule cannot absorb the energy of the photon and the photon continues on its path. This results in transmission (provided no other absorption mechanisms are active).▼
Most of the time, it is a combination of the above that happens to the light that hits an object. The states in different materials vary in the range of energy that they can absorb. Most glasses, for example, block ultraviolet (UV) light. What happens is the electrons in the glass absorb the energy of the photons in the UV range while ignoring the weaker energy of photons in the visible light spectrum. But there are also existing special [[glass]] types, like special types of [[borosilicate glass]] or quartz that are UV-permeable and thus allow a high transmission of
▲*A molecule absorbs the photon, some of the energy may be lost via [[luminescence]], [[fluorescence]] and [[phosphorescence]].
▲*A molecule absorbs the photon which results in reflection or scattering.
▲*A molecule cannot absorb the energy of the photon and the photon continues on its path. This results in transmission (provided no other absorption mechanisms are active).
Thus, when a material is illuminated, individual photons of light can make the [[valence
▲Most of the time, it is a combination of the above that happens to the light that hits an object. The states in different materials vary in the range of energy that they can absorb. Most glasses, for example, block ultraviolet (UV) light. What happens is the electrons in the glass absorb the energy of the photons in the UV range while ignoring the weaker energy of photons in the visible light spectrum. But there are also existing special [[glass]] types, like special types of [[borosilicate glass]] or quartz that are UV-permeable and thus allow a high transmission of ultra violet light.
▲Thus, when a material is illuminated, individual photons of light can make the [[valence electrons]] of an atom transition to a higher electronic [[energy level]]. The photon is destroyed in the process and the absorbed radiant energy is transformed to electric potential energy. Several things can happen then to the absorbed energy: it may be re-emitted by the electron as [[radiant energy]] (in this case the overall effect is in fact a scattering of light), dissipated to the rest of the material (i.e. transformed into [[heat]]), or the electron can be freed from the atom (as in the [[photoelectric effect|photoelectric]] and [[Compton effect|Compton]] effects).
▲===Infrared: Bond stretching===
[[Image:1D normal modes (280 kB).gif|thumb|250px|Normal modes of vibration in a crystalline solid]]
The primary physical mechanism for storing mechanical energy of motion in condensed matter is through [[heat]], or [[thermal energy]]. Thermal energy manifests itself as energy of motion. Thus, heat is motion at the atomic and molecular levels. The primary mode of motion in [[crystalline]] substances is [[vibration]]. Any given atom will vibrate around some [[mean]] or average [[position (vector)|position]] within a crystalline structure, surrounded by its nearest neighbors. This vibration in two dimensions is equivalent to the [[oscillation]] of a clock's pendulum. It swings back and forth [[symmetrical]]ly about some mean or average (vertical) position. Atomic and molecular vibrational frequencies may average on the order of 10<sup>12</sup> [[cycles per second]] ([[Terahertz radiation#Natural|Terahertz radiation]]).
When a light wave of a given frequency strikes a material with particles having the same or (resonant) vibrational frequencies,
If the object is transparent, then the light waves are passed on to neighboring atoms through the bulk of the material and re-emitted on the opposite side of the object. Such frequencies of light waves are said to be
=== Transparency in insulators ===
An object may be not transparent either because it reflects the incoming light or because it absorbs the incoming light. Almost all solids reflect a part and absorb a part of the incoming light.
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Most [[Insulator (electricity)|insulators]] (or [[dielectric]] materials) are held together by [[ionic bond]]s. Thus, these materials do not have free [[conduction electrons]], and the bonding electrons reflect only a small fraction of the incident wave. The remaining frequencies (or wavelengths) are free to propagate (or be transmitted). This class of materials includes all [[ceramic materials|ceramics]] and [[glass]]es.
If a dielectric material does not include light-absorbent additive molecules (pigments, dyes, colorants), it is usually transparent to the spectrum of visible light.
Most liquids and aqueous solutions are highly transparent. For example, water, cooking oil, rubbing alcohol, air, and natural gas are all clear. Absence of structural defects (voids, cracks, etc.) and molecular structure of most liquids are chiefly responsible for their excellent optical transmission. The ability of liquids to "heal" internal defects via viscous flow is one of the reasons why some fibrous materials (e.g., paper or fabric) increase their apparent transparency when wetted. The liquid fills up numerous voids making the material more structurally homogeneous.{{Citation needed|date=July 2013}}
Light scattering in an ideal defect-free [[crystalline]] (non-metallic) solid
== Optical waveguides ==
{{Main|Optical fiber}}
[[Image:Optical-fibre.svg|thumb|right|Propagation of light through a [[Image:Laser in fibre.jpg|thumb|right|A laser beam bouncing down an [[Acrylic glass|acrylic]] rod, illustrating the total internal reflection of light in a multimode optical fiber]]
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An optical fiber is a [[cylindrical]] dielectric waveguide that transmits light along its axis by the process of [[total internal reflection]]. The fiber consists of a [[core (optical fiber)|core]] surrounded by a [[Cladding (fiber optics)|cladding]] layer. To confine the optical signal in the core, the [[refractive index]] of the core must be greater than that of the cladding. The refractive index is the parameter reflecting the [[speed of light]] in a material. (Refractive index is the ratio of the speed of light in vacuum to the speed of light in a given medium. The refractive index of vacuum is therefore 1.) The larger the refractive index, the more slowly light travels in that medium. Typical values for core and cladding of an optical fiber are 1.48 and 1.46, respectively.{{Citation needed|date=April 2021}}
When light traveling in a dense medium hits a boundary at a steep angle, the light will be completely reflected. This effect, called [[total internal reflection]], is used in optical fibers to confine light in the core. Light travels along the fiber bouncing back and forth off of the boundary. Because the light must strike the boundary with an angle greater than the [[total internal reflection|critical angle]], only light that enters the fiber within a certain range of angles will be propagated. This range of angles is called the [[acceptance cone]] of the fiber. The size of this acceptance cone is a function of the refractive index difference between the fiber's core and cladding. [[Optical]] [[waveguides]] are used as components in integrated optical circuits (e.g., combined with lasers or [[light-emitting diodes]], LEDs) or as the transmission medium in local and long
=== Mechanisms of attenuation ===
[[File:Silica core fiber minimum attenuation.jpg|thumb|Experimentally measured record low attenuation of silica core optical fiber. At 1,550 nm, wavelength attenuation components are determined as follows: Rayleigh scattering loss ~ 0.1200 dB/km, infrared absorption loss ~ 0.0150 dB/km, impurity absorption loss ~ 0.0047 dB/km, waveguide imperfection loss ~ 0.0010 dB/km.<ref>{{Cite journal |last1=Khrapko |first1=R. |last2=Logunov |first2=S. L. |last3=Li |first3=M. |last4=Matthews |first4=H. B. |last5=Tandon |first5=P. |last6=Zhou |first6=C. |date=2024-04-15 |title=Quasi Single-Mode Fiber With Record-Low Attenuation of 0.1400 dB/km |journal=IEEE Photonics Technology Letters |volume=36 |issue=8 |pages=539–542 |doi=10.1109/LPT.2024.3372786 |issn=1041-1135|doi-access=free |bibcode=2024IPTL...36..539K }}</ref>|260x260px]]
[[Attenuation]] in [[Optical fiber|fiber optics]], also known as ''transmission loss'', is the reduction in intensity of the light beam (or signal) with respect to distance traveled through a transmission medium. It is an important factor limiting the transmission of a signal across large distances. [[Attenuation
In optical fibers, the main source of attenuation is [[scattering]] from molecular level irregularities, called [[Rayleigh scattering]],<ref>I. P. Kaminow, T. Li (2002), Optical fiber telecommunications IV, [https://books.google.com/books?id=GlxnCiQlNwEC&pg=PA223 Vol. 1, p. 223] {{webarchive|url=https://web.archive.org/web/20130527231335/http://books.google.com/books?id=GlxnCiQlNwEC&q&f=false&pg=PA223 |date=2013-05-27 }}</ref> due to structural disorder and compositional fluctuations of the [[Amorphous solid|glass structure]]. This same phenomenon is seen as one of the limiting factors in the transparency of infrared missile domes.<ref>{{cite journal|author1=Archibald, P.S. |author2=Bennett, H.E. |editor-first1=Stephen A. |editor-first2=Geoffery |editor-last1=Benton |editor-last2=Knight |name-list-style=amp |title=Scattering from infrared missile domes|bibcode=1978SPIE..133...71A|journal=Opt. Eng.|series=Optics in Missile Engineering |volume=17|page=647|year=1978|doi=10.1117/12.956078|s2cid=173179565 }}</ref> Further attenuation is caused by light absorbed by residual materials, such as metals or water ions, within the fiber core and inner cladding. Light leakage due to bending, splices, connectors, or other outside forces are other factors resulting in attenuation. At high optical powers, scattering can also be caused by nonlinear optical processes in the fiber.<ref>{{cite journal|author=Smith, R.G.|title=Optical power handling capacity of low loss optical fibers as determined by stimulated Raman and Brillouin scattering|journal=Appl. Opt.|volume=11|issue=11|pages=2489–94|year=1972|doi=10.1364/AO.11.002489|pmid=20119362|bibcode=1972ApOpt..11.2489S}}</ref>
==As camouflage==▼
▲== As camouflage ==
[[File:Expl0469 - Flickr - NOAA Photo Library.jpg|thumb|upright|Many animals of the open sea, like this ''[[Aurelia labiata]]'' jellyfish, are largely transparent.]]
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[[glass frog]]s of the South American rain forest, which have translucent skin and pale greenish limbs.<ref>{{cite web|last=Naish|first=D.|title=Green-boned glass frogs, monkey frogs, toothless toads|url=http://scienceblogs.com/tetrapodzoology/2007/11/09/green-boned-glass-frogs/|work=Tetrapod zoology|publisher=scienceblogs.com|access-date=14 February 2013|url-status=live|archive-url=https://web.archive.org/web/20121111125205/http://scienceblogs.com/tetrapodzoology/2007/11/09/green-boned-glass-frogs/|archive-date=11 November 2012}}</ref> Several Central American species of clearwing ([[Ithomiini|ithomiine]]) butterflies and many [[dragonfly|dragonflies]] and allied [[insect]]s also have wings which are mostly transparent, a form of [[crypsis]] that provides some protection from predators.{{Citation needed|date=April 2021}}
== See also ==
{{div col|colwidth=22em}}
* [[Brillouin scattering]]
* [[Clarity meter]]
* [[Colloidal crystal]]
* [[Haze (optics)]]
* [[Light scattering]]
* [[Pellicle mirror]]
* [[Photonic crystal]]
* [[Transparent metals]]
* [[Turbidity]]
{{div col end}}
== References ==
{{
== Further reading ==
* ''Electrodynamics of continuous media'', Landau, L. D., Lifshits. E.M. and Pitaevskii, L.P., (Pergamon Press, Oxford, 1984)
* ''Laser Light Scattering: Basic Principles and Practice'' Chu, B., 2nd Edn. (Academic Press, New York 1992)
* ''Solid State Laser Engineering'', W. Koechner (Springer-Verlag, New York, 1999)
* ''Introduction to Chemical Physics'', J.C. Slater (McGraw-Hill, New York, 1939)
* ''Modern Theory of Solids'', F. Seitz, (McGraw-Hill, New York, 1940)
* ''Modern Aspects of the Vitreous State'', J.D.MacKenzie, Ed. (Butterworths, London, 1960)
== External links ==
{{Commons category|Transparency}}
{{Commons category|Transparent mediums}}
* [http://www.schott.com/tubing/english/products/properties/uv-stability.html UV stability]
* [https://web.archive.org/web/20090121035424/http://sol.sci.uop.edu/~jfalward/physics17/chapter12/chapter12.html Properties of Light]
* [http://teaching.shu.ac.uk/hwb/chemistry/tutorials/molspec/uvvisab1.htm UV-Vis Absorption]
* [https://web.archive.org/web/20090122074601/http://www.cem.msu.edu/~reusch/VirtualText/Spectrpy/InfraRed/infrared.htm Infrared Spectroscopy]
* [http://www.soest.hawaii.edu/~zinin/Zi-Brillouin.html Brillouin Scattering]
* [http://www.ikts.fhg.de/business/strukturkeramik/basiswerkstoffe/oxidkeramik/transparentkeramik_en.html Transparent Ceramics]
* [http://science.howstuffworks.com/question476.htm Bulletproof Glass]
* [http://science.howstuffworks.com/transparent-aluminum-armor.htm Transparent ALON Armor]
* [https://web.archive.org/web/20090415161723/http://www.harricksci.com/infoserver/optical%20materials.cfm Properties of Optical Materials]
* [https://web.archive.org/web/20090615050703/http://science.howstuffworks.com/question404.htm What makes glass transparent ?]
* [http://www.rp-photonics.com/brillouin_scattering.html Brillouin scattering in optical fiber]
* [http://www.ausairpower.net/TE-IR-Guidance.html Thermal IR Radiation and Missile Guidance]
{{Glass science}}
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{{DEFAULTSORT:Transparent Materials}}
[[Category:Glass engineering and science]]▼
[[Category:Transparent materials| ]]
[[Category:
[[Category:Physical properties]]
▲[[Category:Glass engineering and science]]
[[Category:Dimensionless numbers of physics]]
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