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Moreover, this strategy, enables synthesis of linear block copolymer structures that are not accessible via sequential monomer addition. Even for common A-b-B structures, sequential block copolymerization gives access to well defined
block copolymers only if the crossover reaction rate constant is significantly higher than the rate constant of the homopolymerization
of the second monomer, i.e., k<sub>AA</sub> >> k<sup>BB</
===Star Shaped Polymers===
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