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==Enumeration==
Because of their applications in hierarchical clustering, the most natural [[graph enumeration]] problem on unrooted binary trees is to count the number of trees with ''n'' labeled leaves and unlabeled internal nodes. An unrooted binary tree on ''n'' labeled leaves can be formed by connecting the ''n''th leaf to a new node in the middle of any of the edges of an unrooted binary tree on ''n'' − 1 labeled leaves. There are 2''n'' −
:<math>(2n-5)!!=\frac{(2n-4)!}{(n-2)!2^{n-2}}.</math><ref>{{harvtxt|Balding|Bishop|Cannings|2007}}.</ref>
The numbers of trees on 2, 3, 4, 5, ... labeled leaves are
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