Anionic addition polymerization: Difference between revisions

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The most commercially useful of these initiators has been the [[alkyllithium]] initiators. They are primarily used for the polymerization of styrenes and dienes.<ref name="Quirk"/>
 
Monomers activated by strong electronegative groups may be initiated even by weak anionic or neutral nucleophiles (i.e. amines, phosphines). Most prominent example is the curing of cyanoacrylate, which constitutes the basis for [[superglue]]. Here, only traces of basic impurities are sufficient to induce an anionic addition polymerization or [[zwitterionic addition polymerization]], respectively.<ref>Pepper, D.C. Zwitterionic Chain Polymerizations of Cyanoacrylates. ''Macromolecular Symposia''; '''1992''',''60'',pp. 267-277. {{doi|10.1002/masy.19920600124/abstract}}</ref>
 
== Propagation ==