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===Transition metal clusters===
Transition metal clusters use the d orbitals for [[Chemical bond|bonding]]. Thus, they have up to nine bonding orbitals, instead of only the four present in boron and main group clusters.<ref name=king>{{cite journal|title=Chemical Applications of Group Theory and Topology.7. A Graph-Theoretical Interpretation of the Bonding Topology in Polyhedral Boranes, Carboranes, and Metal Clusters|last1=King |first1=R. B. |last2=Rouvray |first2=D. H.|journal=[[J. Am. Chem. Soc.]]|year=1977|volume=99|issue=24|pages=7834–7840|doi=10.1021/ja00466a014}}</ref><ref name=RCR>{{cite journal|last1=Kostikova |first1=G. P. |last2=Korolkov |first2=D. V.|title=Electronic Structure of Transition Metal Cluster Complexes with Weak- and Strong-field Ligands|journal=Russ. Chem. Rev.|year=1985|volume=54|issue=4|pages=591–619|doi=10.1070/RC1985v054n04ABEH003040|bibcode = 1985RuCRv..54..344K |s2cid=250797537 }}</ref> PSEPT also applies to [[metallaborane]]s
===Clusters with interstitial atoms===
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