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One example of a formal [3+3]cycloaddition between a cyclic [[enone]] and an [[enamine]] catalyzed by [[N-Butyllithium|''n''-butyllithium]] is a [[Stork enamine reaction|Stork enamine]] / [[nucleophilic addition|1,2-addition]] [[cascade reaction]]:<ref>{{cite journal | last = Movassaghi | first = Mohammad |author2=Bin Chen | title = Stereoselective Intermolecular Formal [3+3] Cycloaddition Reaction of Cyclic Enamines and Enones | journal = [[Angew. Chem. Int. Ed.]] | volume = 46 | pages = 565&ndash;568 | year = 2007 | doi = 10.1002/anie.200603302 | pmid = 17146819 | issue = 4 | pmc=3510678}}</ref>
 
[[Image:3+3- cycloaddition - cyclic iminium to cyclic enone.svg|center|600px500px|IntermolecularAn Formalintermolecular formal [3+3] Cycloadditioncycloaddition Reactionbetween an cyclic iminium chloride and cyclopentenone.]]
 
===Iron-catalyzed 2+2 olefin cycloaddition===