Stretchable microelectrode array: Difference between revisions

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==='''Material Innovation'''===
* '''Electronic Fillers''': This is the oldest approach to making an [[elastomeric]] material elastically stretchable. In principle, rigid and [[electrically conductive]] materials and mixed with an elastomeric [[polymer]] before curing to create stretchable composites. If the concentration of the electrically conductive filler is high enough they form a mesh-like [[percolation]] network that facilitates the free movement of charge carriers (ions, electrons) through contact junctions. The minimum concentration of the electronic filler material that is required to create conductive pathways for [[charge carrier]] transport through the elastomer <ref>{{cite journal |last1=Kyrylyuk, A.|first1=Andriy V., and P. |last2=van der Schoot. "Proc.|first2=Paul Natl.|title=Continuum Acad.percolation Sci.of USA."carbon nanotubes in polymeric and colloidal media |journal=Proceedings of the National Academy of Sciences of|date=17 theJune United2008 States|volume=105 of|issue=24 America,|pages=8221–8226 vol|doi=10. 105, 2008, p1073/pnas.0711449105 8221.}}</ref> is called the [[percolation threshold]].<ref>"Percolation{{cite Threshold."book ScienceDirect, Elsevier, www|doi=10.sciencedirect.com/topics1016/engineering/percolationB978-threshold1-895198-95-9.50011-X Accessed|chapter=Structure 10and Nov.Distribution 2024.of Non-Migrating Antistatics |title=Handbook of Antistatics |date=2016 |pages=117–127 |isbn=978-1-895198-95-9 |editor1-first=Jürgen |editor1-last=Pionteck |editor2-first=George |editor2-last=Wypych }}</ref> The [[percolation threshold]] is usually indicated as weight percentage (wt%) or volume percentage (vol%) of the filler material, and ranges from less than 1wt% for high aspect ration carbon [[nanotubes]] to over 15wt%. The type of filler materials ranges from metals in powder or [[nanowire]] form, [[carbon]] as [[graphite]] or [[nanotubes]], to electrically conducting polymers.
* '''‘Wavy’ [[Nanowires]] and Nanoribbons''': The spontaneous formation of wavy patterns of aligned [[buckles]] that is caused by the deposition of a thin gold film on the surface of the [[elastomer]] [[PDMS]] was first described by the group of George Whitesides at Harvard University in 2000.<ref>Huck, Wilhelm T. S., et al. "Ordering of Spontaneously Formed Buckles on Planar Surfaces." Langmuir, vol. 16, no. 7, 2000, pp. 3497-3501.</ref> The gold was deposited on warmed PDMS (100 °C), and, upon cooling and the associated thermal [[shrinkage]] of the elastomer, the gold film comes under compressive stress which is relieved by creating [[buckles]]. In subsequent years, the group of John Rogers at the University of Urbana Champaign (now at Northwestern University) has developed the technology to bond very thin silicon ribbons to a pre-stretched [[PDMS]] membrane. Upon relaxation of the per-stretch, the compressive [[mechanical stress]] in the [[silicon]] ribbons is relieved by creating wavy buckles in the PDMS. As silicon is a brittle material, the ribbons need to very thin (about 100nm) to stay intact during buckling.<ref>Kim, Dae-Hyeong, and John A. Rogers. "Stretchable Electronics: Materials Strategies and Devices." Advanced Materials, vol. 20, no. 24, 2008, pp. 4887-4892.</ref>
* '''Liquid Metals''': A [[metal]] or [[alloy]] that is liquid at room temperature can be enclosed in [[PDMS]] and used as a stretchable [[conductor]]. [[Mercury (element)|Mercury]] is the only pure metal that is liquid at room temperature but has limited application due to its [[neurotoxicity]]. Cesium melts at 28.5°C, but reacts violently when exposed to air and is therefore not suitable for this application. Most researchers therefore use an [[eutectic]] mixture of Indium and Gallium, so called EGaIn, which has a melting point is 15.7°C and consists of 75.5% Gallium and 24.5% Indium. A eutectic mixture of Ga (68.5%), In (21.5%) and Sn (10.0%), also known as [[Galinstan]], is another popular choice and has a melting point of 10.5°C.