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→Other: Fix minor error: link to (4+3) cycloaddition was incorrectly labelled a [4+3] cycloaddition |
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[[William von Eggers Doering|Doering]] (in a personal communication to [[Robert Burns Woodward|Woodward]]) reported that [[Fulvalene (compound class)|heptafulvalene]] and tetracyanoethylene can react in a suprafacial-antarafacial [14 + 2]-cycloaddition. However, this reaction was later found to be stepwise, as it also produced the Woodward-Hoffmann forbidden suprafacial-suprafacial product under kinetic conditions.
<ref>{{
last2=Gleason|first2=James|
date=2022-06-07|
title=Do Antarafacial Cycloadditions Occur? Cycloaddition of Heptafulvalene with Tetracyanoethylene|
url=https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202201418|
journal=Chemistry:
doi=10.1002/chem.202201418|pmid=35671245 }}
</ref>
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