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On a molecular scale, there are two main competing reaction processes involved in the degradation of [[cellulose]], or wood fuels, in [[wildfire]]s. When there is a low amount of moisture in a cellulose fiber, [[volatilization]] of the fuel occurs; this process will generate intermediate gaseous products that will ultimately be the source of [[combustion]]. When moisture is present—or when enough heat is being carried away from the fiber, [[charring]] occurs. The [[chemical kinetics]] of both reactions indicate that there is a point at which the level of moisture is low enough—and/or heating rates high enough—for combustion processes to become self-sufficient. Consequently, changes in wind speed, direction, moisture, temperature, or [[lapse rate]] at different levels of the atmosphere can have a significant impact on the behavior and growth of a wildfire. Since the wildfire acts as a heat source to the atmospheric flow, the wildfire can modify local [[advection]] patterns, introducing a [[Feedback|feedback loop]] between the fire and the atmosphere.<ref name="Sullivan wildfire">{{cite journal|last=Sullivan|first=Andrew L.|title=Wildland surface fire spread modelling, 1990–2007. 1: Physical and quasi-physical models|journal=International Journal of Wildland Fire|date=June 2009|volume=18|issue=4|page=349|doi=10.1071/WF06143|arxiv=0706.3074|s2cid=16173400}}</ref>
A simplified two-dimensional model for the spread of wildfires that used [[convection]] to represent the effects of wind and terrain, as well as [[Thermal radiation|radiative heat transfer]] as the dominant method of heat transport led to [[reaction–diffusion system]]s of [[partial differential equation]]s.<ref name="Asensio-2002-WFM">{{cite journal|author1=Asensio, M. I. |author2=L. Ferragut |name-list-style=amp |title=On a wildland fire model with radiation|journal=International Journal for Numerical Methods in Engineering|volume=54|issue=1 |pages=137–157|year=2002|doi=10.1002/nme.420|bibcode = 2002IJNME..54..137A |s2cid=122302719 }}</ref><ref name="Mandel-2008-WMD">{{cite journal|author=Mandel, Jan, [[Lynn Schreyer|Lynn S. Bennethum]], Jonathan D. Beezley, [[Janice Coen|Janice L. Coen]], Craig C. Douglas, Minjeong Kim, and Anthony Vodacek|title=A wildfire model with data assimilation|journal=Mathematics and Computers in Simulation|volume=79|pages=584–606|year=2008|doi=10.1016/j.matcom.2008.03.015|arxiv=0709.0086|bibcode=2007arXiv0709.0086M|issue=3|s2cid=839881}}</ref> More complex models join numerical weather models or [[computational fluid dynamics]] models with a wildfire component which allow the feedback effects between the fire and the atmosphere to be estimated.<ref name="Sullivan wildfire"/> The additional complexity in the latter class of models translates to a corresponding increase in their computer power requirements. In fact, a full three-dimensional treatment of [[combustion]] via [[direct numerical simulation]] at scales relevant for atmospheric modeling is not currently practical because of the excessive computational cost such a simulation would require. Numerical weather models have limited forecast skill at spatial resolutions under {{convert|1|km|mi|1|sp=us}}, forcing complex wildfire models to parameterize the fire in order to calculate how the winds will be modified locally by the wildfire, and to use those modified winds to determine the rate at which the fire will spread locally.<ref name="Clark-1996-CAFb">{{cite journal|author=Clark, T. L., M. A. Jenkins, J. Coen, and David Packham|title=A coupled atmospheric-fire model: Convective Froude number and dynamic fingering|journal=International Journal of Wildland Fire|volume=6|pages=177–190|year=1996|doi=10.1071/WF9960177|issue=4|url=https://zenodo.org/record/1236052}}</ref><ref name="Clark-1996-CAF">{{cite journal|author=Clark, Terry L., Marry Ann Jenkins, Janice Coen, and David Packham|title=A coupled atmospheric-fire model: Convective feedback on fire line dynamics|journal=Journal of Applied Meteorology|volume=35|pages=875–901|year=1996|doi=10.1175/1520-0450(1996)035<0875:ACAMCF>2.0.CO;2|bibcode=1996JApMe..35..875C|issue=6|doi-access=free}}</ref><ref name="Rothermel-1972-MMP">{{cite web |author=Rothermel, Richard C. |date=January 1972 |title=A mathematical model for predicting fire spread in wildland fires
== See also ==
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