Revision as of 16:34, 29 March 2014 edit Trappist the monk (talk \| contribs) Administrators 494,559 edits m Fix CS1 deprecated coauthor parameter errors using AWB ← Previous edit		Revision as of 13:46, 21 August 2014 edit undo Daniblanco (talk \| contribs) 328 edits The reverse reaction of an addition is an elimination (and viceversa). Thus, cycloelimination is the best term for the reverse reaction of a cycloaddition (see http://www.chem.qmul.ac.uk/iupac/gtpoc/CoCy.html#40) Next edit →
Line 122: </ref> ==Cycloelimination== ~~==Cycloreversion==~~ While 1,2,3-triazoles are thermally and kinetically stable, polymers containing triazoles are reported to undergo a [[mechanochemistry\|mechanochemically]]-induced 1,3-dipolar ~~cycloreversion~~cycloelimination using [[sonochemistry\|ultrasound]]. The resulting azide and alkyne can be cycloadded upon addition of CuI.<ref name=Brantley>{{cite journal\|last=Brantley\|first=J. N.\|author2=Wiggins, K. M.\|author3= Bielawski, C. W.\|title=Unclicking the Click: Mechanically Facilitated 1,3-Dipolar Cycloreversions\|journal=Science\|date=15 September 2011\|year=2011\|month=September\|volume=333\|issue=6049\|pages=1606–1609\|doi=10.1126/science.1207934\|url=http://www.sciencemag.org.proxy.lib.umich.edu/content/333/6049/1606.full\|accessdate=23 May 2013}}</ref> ==References==

Azide-alkyne Huisgen cycloaddition: Difference between revisions