Multipolar exchange interaction: Difference between revisions

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:<math> Y_{2}^{+1}=\sqrt{2}(Y_{1}^{0}Y_{1}^{+1}+Y_{1}^{+1}Y_{1}^{0}) </math>
:<math> Y_{2}^{+2}=2Y_{1}^{+1}Y_{1}^{+1} </math>
If so, a quadrupole-quadrupole interaction (see next section) can be considered as a two stepsteps dipole-dipole interaction. For example, <math> Y_{2_{i}}^{+2_{i}}Y_{2_{j}}^{-2_{j}}=4Y_{1_{i}}^{+1_{i}}Y_{1_{i}}^{+1_{i}}Y_{1_{j}}^{-1_{j}}Y_{1_{j}}^{-1_{j}} </math>, so the one step quadrupole transiton <math> Y_{2_{i}}^{+2_{i}} </math> on site <math> i </math> now becomes a two steps of dipole transition <matmath> Y_{1_{i}}^{+1_{i}}Y_{1_{i}}^{+1_{i}} </math>. However, it is not a perturbation expansion but just a mathematical technique. The high rank multi-exchange terms are not necessarily smaller than low rank terms. In many cases, high rank terms are more important than low rank terms.<ref name="Review"/>
 
== Multipolar Exchange Interactions ==