Introduction to entropy: Difference between revisions

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* [[Entropy (energy dispersal)|'''Dispersal''']]: [[Edward A. Guggenheim]] proposed an ordinary language interpretation of entropy that may be rendered as 'dispersal of modes of microscopic motion throughout their accessible range'.<ref name="Dugdale 101">Dugdale, J.S. (1996). ''Entropy and its Physical Meaning'', Taylor & Francis, London, {{ISBN|0748405682}}, Dugdale cites only Guggenheim, on page 101.</ref><ref name="Guggenheim1949">Guggenheim, E.A. (1949), Statistical basis of thermodynamics, ''Research: A Journal of Science and its Applications'', '''2''', Butterworths, London, pp. 450–454; p. 453, "If instead of entropy one reads number of accessible states, or spread, the physical significance becomes clear."</ref> Later, along with a criticism of the idea of entropy as 'disorder', the dispersal interpretation was advocated by [[Frank L. Lambert]],<ref name=Lambert/><ref name="Lambert2005">{{cite journal |last1=Kozliak |first1=Evguenii I. |last2=Lambert |first2=Frank L.|date=2005 |title=“Order-to-Disorder” for Entropy Change? Consider the Numbers!|journal=Chem. Educator |volume=10 |pages= 24-25|access-date=December 13, 2020}}</ref> and is used in some student textbooks.<ref>For example: Atkins, P. W., de Paula J. Atkins' Physical Chemistry, 2006, W.H. Freeman and Company, 8th edition, {{ISBN|9780716787594}}. Brown, T. L., H. E. LeMay, B. E. Bursten, C.J. Murphy, P. Woodward, M.E. Stoltzfus 2017. Chemistry: The Central Science, 10th ed. Prentice Hall, 1248pp, {{ISBN|9780134414232}}. Ebbing, D.D., and S. D. Gammon, 2017. General Chemistry, 11th ed. Centage Learning 1190pp, {{ISBN|9781305580343}}. Petrucci, Herring, Madura, Bissonnette 2011 General Chemistry: Principles and Modern Applications, 10th edition, 1426 pages, Pearson Canada {{ISBN|9780132064521}}.</ref>
 
:The interpretation properly refers to dispersal in abstract microstate spaces, but it may be loosely visualised in some simple examples of spatial spread of matter or energy. If a partition is removed from between two different gases, the molecules of each gas spontaneously disperse as widely as possible into their respectively newly accessible volumes; this may be thought of as mixing. If a partition, that blocks heat transfer between two bodies of different temperatures, is removed so that heat can pass between the bodies, then energy spontaneously disperses or spreads as heat from the hotter to the colder.
 
:Beyond such loose visualizations, in a general thermodynamic process, considered microscopically, spontaneous dispersal occurs in abstract microscopic [[phase space]]. According to Newton's and other laws of motion, phase space provides a systematic scheme for the description of the diversity of microscopic motion that occurs in bodies of matter and radiation. The second law of thermodynamics may be regarded as quantitatively accounting for the intimate interactions, dispersal, or mingling of such microscopic motions. In other words, entropy may be regarded as measuring the extent of diversity of motions of microscopic constituents of bodies of matter and radiation in their own states of internal thermodynamic equilibrium.
===Information entropy and Statistical mechanics===
 
* [[Entropy (order and disorder)|'''As a measure of disorder''']]: Traditionally, 20th century textbooks have introduced [[Entropy (order and disorder)|entropy as order and disorder]] so that it provides "a measurement of the disorder or randomness of a system". It has been argued that ambiguities in, and arbitrary interpretations of, the terms used (such as "disorder" and "chaos") contribute to widespread confusion and can hinder comprehension of entropy for most students. On the other hand, in a convenient though arbitrary interpretation, "disorder" may be sharply defined as the [[Entropy (information theory)|Shannon entropy]] of the probability distribution of microstates given a particular macrostate,<ref name="Callen1985">{{cite book|title=Thermodynamics and an Introduction to Thermostatistics|last=Callen|first=Herbert B.|date=1985|publisher=John Wiley & Sons|isbn=0-471-86256-8|edition=2nd|___location=New York|author-link=Herbert Callen}}</ref>{{rp|379}} in which case the [[Entropy in thermodynamics and information theory|connection of "disorder" to thermodynamic entropy]] is straightforward, but arbitrary and not immediately obvious to anyone unfamiliar with information theory.
 
===Information entropy and Statistical mechanics===
:The interpretation properly refers to dispersal in abstract microstate spaces, but it may be loosely visualised in some simple examples of spatial spread of matter or energy. If a partition is removed from between two different gases, the molecules of each gas spontaneously disperse as widely as possible into their respectively newly accessible volumes; this may be thought of as mixing. If a partition, that blocks heat transfer between two bodies of different temperatures, is removed so that heat can pass between the bodies, then energy spontaneously disperses or spreads as heat from the hotter to the colder.
 
* [[Entropy (order and disorder)|'''As a measure of disorder''']]: Traditionally, 20th century textbooks have introduced [[Entropy (order and disorder)|entropy as order and disorder]] so that it provides "a measurement of the disorder or randomness of a system". It has been argued that ambiguities in, and arbitrary interpretations of, the terms used (such as "disorder" and "chaos") contribute to widespread confusion and can hinder comprehension of entropy for most students. On the other hand, in a convenient though arbitrary interpretation, "disorder" may be sharply defined as the [[Entropy (information theory)|Shannon entropy]] of the probability distribution of microstates given a particular macrostate,<ref name="Callen1985">{{cite book|title=Thermodynamics and an Introduction to Thermostatistics|last=Callen|first=Herbert B.|date=1985|publisher=John Wiley & Sons|isbn=0-471-86256-8|edition=2nd|___location=New York|author-link=Herbert Callen}}</ref>{{rp|379}} in which case the [[Entropy in thermodynamics and information theory|connection of "disorder" to thermodynamic entropy]] is straightforward, but arbitrary and not immediately obvious to anyone unfamiliar with information theory.
:Beyond such loose visualizations, in a general thermodynamic process, considered microscopically, spontaneous dispersal occurs in abstract microscopic [[phase space]]. According to Newton's and other laws of motion, phase space provides a systematic scheme for the description of the diversity of microscopic motion that occurs in bodies of matter and radiation. The second law of thermodynamics may be regarded as quantitatively accounting for the intimate interactions, dispersal, or mingling of such microscopic motions. In other words, entropy may be regarded as measuring the extent of diversity of motions of microscopic constituents of bodies of matter and radiation in their own states of internal thermodynamic equilibrium.
 
* '''Missing information''': The idea that information entropy is a measure of how much one does not know about a system is quite useful. Unfortunately, however, it gives less intuitive insight into physical concept of thermodynamic entropy than other approaches to understanding entropy.