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{{short description|For a large class of boundary conditions, all solutions have the same gradient}}
The '''uniqueness theorem''' for [[Poisson's equation]] states that, for a large class of [[boundary condition]]s, the equation may have many solutions, but the gradient of every solution is the same. In the case of [[electrostatics]], this means that there is a unique [[electric field]] derived from a [[Electric potential|potential function]] satisfying Poisson's equation under the boundary conditions.
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==Proof==
:<math>\mathbf{\nabla}
The uniqueness
Suppose that
:<math>\mathbf{\nabla}
:<math>\mathbf{\nabla}^2 \varphi_2 = - \frac{\rho_f}{\epsilon_0}</math>
It follows that <math>\varphi=\varphi_2-\varphi_1</math> is a solution of [[Laplace's equation]] (a special case of [[Poisson's equation]] which equals <math>0</math>) because subtracting the two solutions above gives
:<math>\mathbf{\nabla}
Let us first consider the case where [[Dirichlet boundary condition|Dirichlet boundary conditions]] are specified as <math>\varphi = 0</math> on the boundary of the region. These follow because the boundary conditions and the charge distributions are the same for both 'solutions'.
▲:<math>\mathbf{\nabla}\cdot(\varphi\varepsilon \, \mathbf{\nabla}\varphi)= \varepsilon (\mathbf{\nabla}\varphi)^2</math>
We can now use the [[Vector calculus identities#Divergence 2|vector differential identity]]
Taking the volume integral over all space specified by the boundary conditions gives▼
:<math>\
However, from <math>(1)</math> we know that <math>\nabla^2 \varphi = 0</math> throughout the region so the second term goes to zero
Applying the [[divergence theorem]], the expression can be rewritten as▼
:<math>\
where <math>S_i</math> are boundary surfaces specified by boundary conditions.▼
:<math>
Finally, because the gradient of <math>\varphi</math> is everywhere zero and <math>\varphi</math> is zero on the boundary, <math>\varphi</math> must be zero throughout the whole region. This proves <math>\varphi_1 = \varphi_2</math> and the solutions are identical.
If the [[Neumann boundary condition|Neumann boundary conditions]] had been specified then the normal component of <math>\nabla \phi</math> on the left-hand side of <math>(2)</math> would be zero on the boundary and we would arrive at the same conclusion. In this case, however, the relationship between the solutions is only constrained to a constant factor <math>k</math>, in other words <math>\varphi_1 - \varphi_2 = k</math>, because only the normal derivative of <math>\varphi</math> was specified to be zero.
[[Mixed boundary condition|Mixed boundary conditions]] could be given as long as ''either'' the gradient ''or'' the potential is specified at each point of the proof.
Boundary conditions at infinity also hold as the surface integral in <math>(2)</math> still vanishes at large distances as the integrand decays faster than the surface area grows.
==See also==
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